ICCAS OpenIR
THE APPLICATION OF STRUCTURAL DATA TO THE RESEARCH ON CHEMICAL REACTION PATHWAYS, I. DYNAMIC STEREOCHEMISTRY OF FIVE-COORDINATE MOLYBDENUM COMPOUNDS Mo(L)(5)
Liao Daiqing; Fu Heng; Tang Yougi
1987
Source PublicationACTA PHYSICO-CHIMICA SINICA
ISSN1000-6818
Volume3Issue:5Pages:449-452
AbstractThe principle of structure correlation is applied to 28 crystal structures which contain 44 different five coordinate molybdenum fragments. The tints derived map the reaction pathway for a bimolecular ligand substitution reaction at tetrahedral molybdenum centers. The dihedral angle method from Muetteries and Guggenberger is employed in order to describe the interconversion between the trigonal bipyramidal (TBP) and tit square pramidal (SQP) conformations via the Berry pseudorotation mechanism in the system of Mo (L)(5) complexes. The structure correlation method provides a convincing mapping of the Berry pathway in this paper.
DOI10.3866/PKU.WHXB19870501
Indexed BySCI
Language英语
WOS IDWOS:000207569500001
PublisherPEKING UNIV PRESS
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/73990
Collection中国科学院化学研究所
Corresponding AuthorLiao Daiqing
AffiliationAcad Sinica, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Liao Daiqing,Fu Heng,Tang Yougi. THE APPLICATION OF STRUCTURAL DATA TO THE RESEARCH ON CHEMICAL REACTION PATHWAYS, I. DYNAMIC STEREOCHEMISTRY OF FIVE-COORDINATE MOLYBDENUM COMPOUNDS Mo(L)(5)[J]. ACTA PHYSICO-CHIMICA SINICA,1987,3(5):449-452.
APA Liao Daiqing,Fu Heng,&Tang Yougi.(1987).THE APPLICATION OF STRUCTURAL DATA TO THE RESEARCH ON CHEMICAL REACTION PATHWAYS, I. DYNAMIC STEREOCHEMISTRY OF FIVE-COORDINATE MOLYBDENUM COMPOUNDS Mo(L)(5).ACTA PHYSICO-CHIMICA SINICA,3(5),449-452.
MLA Liao Daiqing,et al."THE APPLICATION OF STRUCTURAL DATA TO THE RESEARCH ON CHEMICAL REACTION PATHWAYS, I. DYNAMIC STEREOCHEMISTRY OF FIVE-COORDINATE MOLYBDENUM COMPOUNDS Mo(L)(5)".ACTA PHYSICO-CHIMICA SINICA 3.5(1987):449-452.
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