ICCAS OpenIR
Self-assembly of a new C-60 compound with a L-glutamid-derived lipid unit: formation of organogels and hierarchically structured spherical particles
Yang, Xingyuan1,2; Zhang, Guanxin1; Zhang, Deqing1; Xiang, Junfeng1; Yang, Ge1,2; Zhu, Daoben1
2011
Source PublicationSOFT MATTER
ISSN1744-683X
Volume7Issue:7Pages:3592-3598
AbstractA new C-60-based low-molecular weight gelator (LMWG 1) with a L-glutamid-derived lipid unit was synthesized and characterized. LMWG 1 can gel toluene, p-xylene and benzene. Moreover, its gelation ability can be further enhanced by addition of an exTTF derivative (compound 2), for which the intermolecular interaction between the C-60 unit in 1 and the exTTF unit in 2 is responsible based on the absorption and NOE difference H-1-NMR spectral studies. Additionally, gelation-induced CD signals are observed for the gel with LMWG 1 and that of LMWG 1 doped with compound 2. Further studies indicate that the self-assembly structures of LMWG 1 in the gel phases can be modulated by the addition of compound 2. In addition, the self-assembly of LMWG 1 in DMSO leads to spherical particles of several microns in size, and the surfaces of these spherical particles are hierarchically structured with nano-fibers. Moreover, the thin-film of spherical particles exhibits water-repellent hydrophobicity.
DOI10.1039/c0sm01109f
Indexed BySCI
Language英语
WOS IDWOS:000288677200068
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:23[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/73926
Collection中国科学院化学研究所
Corresponding AuthorZhang, Deqing
Affiliation1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Organ Solids Lab, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Yang, Xingyuan,Zhang, Guanxin,Zhang, Deqing,et al. Self-assembly of a new C-60 compound with a L-glutamid-derived lipid unit: formation of organogels and hierarchically structured spherical particles[J]. SOFT MATTER,2011,7(7):3592-3598.
APA Yang, Xingyuan,Zhang, Guanxin,Zhang, Deqing,Xiang, Junfeng,Yang, Ge,&Zhu, Daoben.(2011).Self-assembly of a new C-60 compound with a L-glutamid-derived lipid unit: formation of organogels and hierarchically structured spherical particles.SOFT MATTER,7(7),3592-3598.
MLA Yang, Xingyuan,et al."Self-assembly of a new C-60 compound with a L-glutamid-derived lipid unit: formation of organogels and hierarchically structured spherical particles".SOFT MATTER 7.7(2011):3592-3598.
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