ICCAS OpenIR
Synthesis and properties of novel perylenetetracarboxylic diimide derivatives fused with BODIPY units
Feng, Junqian1,2; Wang, Delou1; Wang, Shuangqing3; Zhang, Liangliang1; Li, Xiyou1
2011-04-01
Source PublicationDYES AND PIGMENTS
ISSN0143-7208
Volume89Issue:1Pages:23-28
AbstractTwo novel fluorescent dyes based on perylenetetracarboxylic diimde (PDI) with methylpyridine or methylquinoline group at the carbonyl position were designed and synthesized Their structures were confirmed by (1)H NMR (13)C NMR MS and elementary analysis The resulted new compounds show longer wavelength absorption with relative high extinction coefficient and red-shifted emission with high fluorescence quantum yields These compounds can further react with BF(3) Et(2)O to form novel dyes containing BODIPY (difluoroboradiazaindacene) analogue unit by which both the absorption and emission maximum have been red-shifted further The minimized structures based on density function theory (DFT) calculation show planar configurations for the compounds The calculated molecular orbital correlates well with their red-shifted absorption and emission spectra (C) 2010 Elsevier Ltd All rights reserved
KeywordPerylenetetracarboxylic Diimide Methylquinoline Methylpyridine Bodipy Synthesis Photophysical Properties
DOI10.1016/j.dyepig.2010.08.014
Indexed BySCI
Language英语
WOS IDWOS:000285908100004
PublisherELSEVIER SCI LTD
Citation statistics
Cited Times:13[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/73830
Collection中国科学院化学研究所
Corresponding AuthorLi, Xiyou
Affiliation1.Shandong Univ, Dept Chem, Key Lab Colloid & Interface Chem, Educ Minist, Jinan 250100, Peoples R China
2.Coll Shandong Policeman, Jinan 250014, Peoples R China
3.Chinese Acad Sci, Inst Chem, Key Lab Photochem CAS, Beijing 100800, Peoples R China
Recommended Citation
GB/T 7714
Feng, Junqian,Wang, Delou,Wang, Shuangqing,et al. Synthesis and properties of novel perylenetetracarboxylic diimide derivatives fused with BODIPY units[J]. DYES AND PIGMENTS,2011,89(1):23-28.
APA Feng, Junqian,Wang, Delou,Wang, Shuangqing,Zhang, Liangliang,&Li, Xiyou.(2011).Synthesis and properties of novel perylenetetracarboxylic diimide derivatives fused with BODIPY units.DYES AND PIGMENTS,89(1),23-28.
MLA Feng, Junqian,et al."Synthesis and properties of novel perylenetetracarboxylic diimide derivatives fused with BODIPY units".DYES AND PIGMENTS 89.1(2011):23-28.
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