ICCAS OpenIR
Synthesis, Crystal Structure, and Optical and Photoelectrochemical Properties of a N boolean AND O- Rhenium(I) Complex
Ju, Chuan-Chuan1; Zhang, An-Guo1; Sun, Hao-Ling1; Wang, Ke-Zhi1; Jiang, Wei-Li2; Bian, Zu-Qiang2; Huang, Chun-Hui2
2011-02-28
Source PublicationORGANOMETALLICS
ISSN0276-7333
Volume30Issue:4Pages:709-713
AbstractThe neutral dimer complex Re-7(CO)(6)(BIZ)(2) was directly obtained from a simple reaction between Re(CO)(5)Cl and N boolean AND OH-type ligand 2(l-phenyl-1H-benzoimidazol-2-yl)phenol (HBIZ). The further reaction of Re-2(CO)(6)(BIZ)(2) with pyridine (Py) led to the monomeric Re(CO)(3)(BIZ)(Py), which was characterized by means of single-crystal X-ray diffraction analysis, H-1 NMR, elemental analysis, and UV-visible absorption, photoluminescence, and infrared spectroscopy as well as cyclic voltammetry. The photoelectrochemical properties of Re(CO)(3)(BIZ)(Py) spin-coated film modified indium-tin oxide electrode were investigated, and a large cathodic photocurrent up to 0.55 mu A/cm(2) at-0.3 V bias potential was observed. The LUMO and HOMO energy levels of Re(CO)(3)(BIZ)(Py) were studied by density functional theory calculations. The possible mechanism of the photocurrent generation was discussed.
DOI10.1021/om100311b
Indexed BySCI ; IC
Language英语
WOS IDWOS:000287546600009
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:15[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/73772
Collection中国科学院化学研究所
Corresponding AuthorWang, Ke-Zhi
Affiliation1.Beijing Normal Univ, Coll Chem, Beijing 100875, Peoples R China
2.Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Ju, Chuan-Chuan,Zhang, An-Guo,Sun, Hao-Ling,et al. Synthesis, Crystal Structure, and Optical and Photoelectrochemical Properties of a N boolean AND O- Rhenium(I) Complex[J]. ORGANOMETALLICS,2011,30(4):709-713.
APA Ju, Chuan-Chuan.,Zhang, An-Guo.,Sun, Hao-Ling.,Wang, Ke-Zhi.,Jiang, Wei-Li.,...&Huang, Chun-Hui.(2011).Synthesis, Crystal Structure, and Optical and Photoelectrochemical Properties of a N boolean AND O- Rhenium(I) Complex.ORGANOMETALLICS,30(4),709-713.
MLA Ju, Chuan-Chuan,et al."Synthesis, Crystal Structure, and Optical and Photoelectrochemical Properties of a N boolean AND O- Rhenium(I) Complex".ORGANOMETALLICS 30.4(2011):709-713.
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