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| Synthesis, Crystal Structure, and Optical and Photoelectrochemical Properties of a N boolean AND O- Rhenium(I) Complex | |
| Ju, Chuan-Chuan1; Zhang, An-Guo1; Sun, Hao-Ling1; Wang, Ke-Zhi1; Jiang, Wei-Li2; Bian, Zu-Qiang2; Huang, Chun-Hui2 | |
| 2011-02-28 | |
| Source Publication | ORGANOMETALLICS
 |
| ISSN | 0276-7333 |
| Volume | 30Issue:4Pages:709-713 |
| Abstract | The neutral dimer complex Re-7(CO)(6)(BIZ)(2) was directly obtained from a simple reaction between Re(CO)(5)Cl and N boolean AND OH-type ligand 2(l-phenyl-1H-benzoimidazol-2-yl)phenol (HBIZ). The further reaction of Re-2(CO)(6)(BIZ)(2) with pyridine (Py) led to the monomeric Re(CO)(3)(BIZ)(Py), which was characterized by means of single-crystal X-ray diffraction analysis, H-1 NMR, elemental analysis, and UV-visible absorption, photoluminescence, and infrared spectroscopy as well as cyclic voltammetry. The photoelectrochemical properties of Re(CO)(3)(BIZ)(Py) spin-coated film modified indium-tin oxide electrode were investigated, and a large cathodic photocurrent up to 0.55 mu A/cm(2) at-0.3 V bias potential was observed. The LUMO and HOMO energy levels of Re(CO)(3)(BIZ)(Py) were studied by density functional theory calculations. The possible mechanism of the photocurrent generation was discussed. |
| DOI | 10.1021/om100311b |
| Indexed By | SCI ; IC |
| Language | 英语 |
| WOS ID | WOS:000287546600009 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.iccas.ac.cn/handle/121111/73772 |
| Collection | 中国科学院化学研究所 |
| Corresponding Author | Wang, Ke-Zhi |
| Affiliation | 1.Beijing Normal Univ, Coll Chem, Beijing 100875, Peoples R China 2.Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| Recommended Citation GB/T 7714 | Ju, Chuan-Chuan,Zhang, An-Guo,Sun, Hao-Ling,et al. Synthesis, Crystal Structure, and Optical and Photoelectrochemical Properties of a N boolean AND O- Rhenium(I) Complex[J]. ORGANOMETALLICS,2011,30(4):709-713. |
| APA | Ju, Chuan-Chuan.,Zhang, An-Guo.,Sun, Hao-Ling.,Wang, Ke-Zhi.,Jiang, Wei-Li.,...&Huang, Chun-Hui.(2011).Synthesis, Crystal Structure, and Optical and Photoelectrochemical Properties of a N boolean AND O- Rhenium(I) Complex.ORGANOMETALLICS,30(4),709-713. |
| MLA | Ju, Chuan-Chuan,et al."Synthesis, Crystal Structure, and Optical and Photoelectrochemical Properties of a N boolean AND O- Rhenium(I) Complex".ORGANOMETALLICS 30.4(2011):709-713. |
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