ICCAS OpenIR
Synthesis of Vinyl-Substituted Polypyridyl Ligands through Suzuki-Miyaura Cross-Coupling of Potassium Vinyltrifluoroborate with Bromopolypyridines
Nie, Hai-Jing; Yao, Jiannian; Zhong, Yu-Wu
2011-06-03
Source PublicationJOURNAL OF ORGANIC CHEMISTRY
ISSN0022-3263
Volume76Issue:11Pages:4771-4775
AbstractSuzuki-Miyauni cross-coupling of bromopolypyridines with potassium vinyltrifluoroborate affords vinyl-substituted polypyridyl ligands in moderate to good yields. This reaction allows simple and practical syntheses of numerous vinyl-substituted polypyridines, such as 4'-vinyl-2,2':6',2 ''-terpyridine, 5,5'-divinyl-2,2'-bipyridine, and 4,4'-divinyl-2,2'-bipyridine. In addition, a new ruthenium complex, [Ru(S,5'-divinyl-2,2'-bipyridine)(3)](2+), was synthesized and found to undergo reductive electropolymerization smoothly.
DOI10.1021/jo200590r
Indexed BySCI ; IC ; CCR
Language英语
WOS IDWOS:000291128300053
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:20[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/73736
Collection中国科学院化学研究所
Corresponding AuthorZhong, Yu-Wu
AffiliationChinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Photochem, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Nie, Hai-Jing,Yao, Jiannian,Zhong, Yu-Wu. Synthesis of Vinyl-Substituted Polypyridyl Ligands through Suzuki-Miyaura Cross-Coupling of Potassium Vinyltrifluoroborate with Bromopolypyridines[J]. JOURNAL OF ORGANIC CHEMISTRY,2011,76(11):4771-4775.
APA Nie, Hai-Jing,Yao, Jiannian,&Zhong, Yu-Wu.(2011).Synthesis of Vinyl-Substituted Polypyridyl Ligands through Suzuki-Miyaura Cross-Coupling of Potassium Vinyltrifluoroborate with Bromopolypyridines.JOURNAL OF ORGANIC CHEMISTRY,76(11),4771-4775.
MLA Nie, Hai-Jing,et al."Synthesis of Vinyl-Substituted Polypyridyl Ligands through Suzuki-Miyaura Cross-Coupling of Potassium Vinyltrifluoroborate with Bromopolypyridines".JOURNAL OF ORGANIC CHEMISTRY 76.11(2011):4771-4775.
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