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Synthesis, Structures and Magnetism of Two New 3D Pillared-layer Cerium Mixed Carboxylate Porous Metal-organic Frameworks
Zhu Wen-Hua1,2; Wang Zhe-Ming1; Gao Song1
2011-03-10
Source PublicationCHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN0251-0790
Volume32Issue:3Pages:532-537
AbstractTwo new cerium mixed carboxylate porous metal-organic frameworks, [Ce(2)(fum)(3)(H(2)O)(4)center dot(H(2)bdc)center dot(H(2)O)(2)](n) (1, H(2)fum = fumaric acid, H(2)bdc p-benzenedicarboxylic acid) and [Ce(2)(suc)(2)(ox) (H(2)O)(4)center dot(H(2)O)(4) (4) (2, H(2)suc = succinic acid, H(2)ox = oxalic acid) were synthesized by hydrothermal method with two kinds of carboxylic acid, respectively. They were characterized by elemental analysis, IR, TGA-DTA and single-crystal X-ray diffraction. Complexes 1 and 2 are both 3D porous metal-organic frameworks of pillared-layer type. Complex 1 possesses a 3D framework structure consisting of Ce-fumarate layers pillared by fumarate ligands with intersected channels in two directions between the layers occupied by uncoordinated neutral p-benzenedicarboxylic acid and lattice water molecules. Similar to complex 1, complex 2 is a 3D framework structure with Ce-succinate layers pillared by oxalate ligands, which shows intersected channels in three directions between the layers filled with lattice water molecules.
KeywordMetal-organic Framework Cerium Complex Mixed Carboxylate Magnetism
Indexed BySCI
Language英语
WOS IDWOS:000289041600015
PublisherHIGHER EDUCATION PRESS
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/73492
Collection中国科学院化学研究所
Corresponding AuthorWang Zhe-Ming
Affiliation1.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
2.Hubei Univ, Coll Chem & Chem Engn, Wuhan 430062, Peoples R China
Recommended Citation
GB/T 7714
Zhu Wen-Hua,Wang Zhe-Ming,Gao Song. Synthesis, Structures and Magnetism of Two New 3D Pillared-layer Cerium Mixed Carboxylate Porous Metal-organic Frameworks[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2011,32(3):532-537.
APA Zhu Wen-Hua,Wang Zhe-Ming,&Gao Song.(2011).Synthesis, Structures and Magnetism of Two New 3D Pillared-layer Cerium Mixed Carboxylate Porous Metal-organic Frameworks.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,32(3),532-537.
MLA Zhu Wen-Hua,et al."Synthesis, Structures and Magnetism of Two New 3D Pillared-layer Cerium Mixed Carboxylate Porous Metal-organic Frameworks".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 32.3(2011):532-537.
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