ICCAS OpenIR
Nanometer-Sized Reactor-A Porphyrin-Based Model System for Anion Species
Li, Yong-jun1; Zhao, Ying-jie1; Flood, Amar H.2; Liu, Chao1; Liu, Hui-biao1; Li, Yu-liang1
2011-06-01
Source PublicationCHEMISTRY-A EUROPEAN JOURNAL
ISSN0947-6539
Volume17Issue:27Pages:7499-7505
AbstractAlthough many cagelike molecules can create a catalytic environment for promoting chemical reactions, the construction of receptors that can host anionic species and sensitize their reaction is novel. Here we report the photochemically induced dimerization of the anion radicals of TCNQ (7,7,8,8-tetracyano-para-quinodimethane) in organic solvent under aerobic conditions when they are encapsulated inside a cationic photoactive receptor. There is clear evidence for a rate increase of over two orders of magnitude, photosensitization of the host, and demonstrated turnover of the catalyst.
KeywordAnions Host-guest Systems Photosensitization Porphyrins Reactors
DOI10.1002/chem.201100633
Indexed BySCI ; IC
Language英语
WOS IDWOS:000292211300017
PublisherWILEY-BLACKWELL
Citation statistics
Cited Times:17[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/73326
Collection中国科学院化学研究所
Corresponding AuthorLi, Yong-jun
Affiliation1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Indiana Univ, Dept Chem, Bloomington, IN 47405 USA
Recommended Citation
GB/T 7714
Li, Yong-jun,Zhao, Ying-jie,Flood, Amar H.,et al. Nanometer-Sized Reactor-A Porphyrin-Based Model System for Anion Species[J]. CHEMISTRY-A EUROPEAN JOURNAL,2011,17(27):7499-7505.
APA Li, Yong-jun,Zhao, Ying-jie,Flood, Amar H.,Liu, Chao,Liu, Hui-biao,&Li, Yu-liang.(2011).Nanometer-Sized Reactor-A Porphyrin-Based Model System for Anion Species.CHEMISTRY-A EUROPEAN JOURNAL,17(27),7499-7505.
MLA Li, Yong-jun,et al."Nanometer-Sized Reactor-A Porphyrin-Based Model System for Anion Species".CHEMISTRY-A EUROPEAN JOURNAL 17.27(2011):7499-7505.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Li, Yong-jun]'s Articles
[Zhao, Ying-jie]'s Articles
[Flood, Amar H.]'s Articles
Baidu academic
Similar articles in Baidu academic
[Li, Yong-jun]'s Articles
[Zhao, Ying-jie]'s Articles
[Flood, Amar H.]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Li, Yong-jun]'s Articles
[Zhao, Ying-jie]'s Articles
[Flood, Amar H.]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.