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Rh(I)-Catalyzed Formal [5+1]/[2+2+1] Cycloaddition of 1-Yne-vinylcyclopropanes and Two CO Units: One-Step Construction of Multifunctional Angular Tricyclic 5/5/6 Compounds
Lin, Mu; Li, Feng; Jiao, Lei; Yu, Zhi-Xiang
2011-02-16
Source PublicationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN0002-7863
Volume133Issue:6Pages:1690-1693
AbstractA novel Rh(I)-catalyzed formal [5 + 1]/[2 + 2 + 1] cycloaddition of 1-yne-vinylcydopropanes and two CO units for the construction of multifunctional angular tricyclic 5/5/6 skeletons with one or two adjacent bridgehead quaternary all-carbon stereocenters in one step has been developed. Preliminary density functional theory calculations have been carried out to investigate the reaction mechanism and the substituent effects.
DOI10.1021/ja110039h
Indexed BySCI ; IC ; CCR
Language英语
WOS IDWOS:000287831800021
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:61[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/73284
Collection中国科学院化学研究所
Corresponding AuthorYu, Zhi-Xiang
AffiliationPeking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Lin, Mu,Li, Feng,Jiao, Lei,et al. Rh(I)-Catalyzed Formal [5+1]/[2+2+1] Cycloaddition of 1-Yne-vinylcyclopropanes and Two CO Units: One-Step Construction of Multifunctional Angular Tricyclic 5/5/6 Compounds[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2011,133(6):1690-1693.
APA Lin, Mu,Li, Feng,Jiao, Lei,&Yu, Zhi-Xiang.(2011).Rh(I)-Catalyzed Formal [5+1]/[2+2+1] Cycloaddition of 1-Yne-vinylcyclopropanes and Two CO Units: One-Step Construction of Multifunctional Angular Tricyclic 5/5/6 Compounds.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,133(6),1690-1693.
MLA Lin, Mu,et al."Rh(I)-Catalyzed Formal [5+1]/[2+2+1] Cycloaddition of 1-Yne-vinylcyclopropanes and Two CO Units: One-Step Construction of Multifunctional Angular Tricyclic 5/5/6 Compounds".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 133.6(2011):1690-1693.
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