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Syntheses and Crystal Structures of Two New Bismuth Hydroxyl Borates Containing [Bi2O2](2+) Layers: Bi2O2[B3O5(OH)] and Bi2O2[BO2(OH)]
Cong, Rihong1; Sun, Junliang2; Yang, Tao1; Li, Mingrun2; Liao, Fuhui1; Wang, Yingxia1; Lin, Jianhua1
2011-06-06
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume50Issue:11Pages:5098-5104
AbstractTwo new bismuth hydroxyl borates, Bi2O2[B(3)O5-(OH)] (I) and Bi2O2[BO2(OH)] (II), have been synthesized under hydrothermal conditions. Their structures were determined by single-crystal and powder X-ray diffraction data, respectively. Compound I crystallizes in the orthorhombic space group Pbca with the lattice constants of a = 6.0268(3) angstrom, b = 11.3635(6) angstrom, and c = 19.348(1) angstrom. Compound II crystallizes in the monoclinic space group Cm with the lattice constants of a = 5.4676(6) angstrom, b = 14.6643(5) angstrom, c = 3.9058(1) angstrom, and beta = 135.587(6)degrees. The borate fundamental building block (FBB) in I is a three-ring unit [B3O6(OH)](4-), which connects one by one via sharing corners, forming an infinite zigzag chain along the a direction. The borate chains are further linked by hydrogen bonds, showing as a borate layer within the ab plane. The FBB in II is an isolated [BO2(OH)](2-) triangle, which links to two neighboring FBBs by strong hydrogen bonds, resulting in a borate chain along the a direction. Both compounds contain [Bi2O2](2+) layers, and the [Bi2O2](2+) layers combine with the corresponding borate layers alternatively, forming the whole structures. These two new bismuth borates are the first ones containing [Bi2O2](2+) layers in borates. The appearance of Bi2O2[BO2(OH)] (II) completes the series of compounds Bi2O2[BO2(OH)], Bi2O2CO3, and Bi2O2[NO3(OH)] and the formation of Bi2O2[B3O5(OH)] provides another example in demonstrating the polymerization tendency of borate groups.
DOI10.1021/ic200382b
Indexed BySCI
Language英语
WOS IDWOS:000290978400050
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:29[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/73114
Collection中国科学院化学研究所
Corresponding AuthorWang, Yingxia
Affiliation1.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
2.Stockholm Univ, Inorgan & Struct Chem & Berzelii Ctr EXSELENT Por, SE-10691 Stockholm, Sweden
Recommended Citation
GB/T 7714
Cong, Rihong,Sun, Junliang,Yang, Tao,et al. Syntheses and Crystal Structures of Two New Bismuth Hydroxyl Borates Containing [Bi2O2](2+) Layers: Bi2O2[B3O5(OH)] and Bi2O2[BO2(OH)][J]. INORGANIC CHEMISTRY,2011,50(11):5098-5104.
APA Cong, Rihong.,Sun, Junliang.,Yang, Tao.,Li, Mingrun.,Liao, Fuhui.,...&Lin, Jianhua.(2011).Syntheses and Crystal Structures of Two New Bismuth Hydroxyl Borates Containing [Bi2O2](2+) Layers: Bi2O2[B3O5(OH)] and Bi2O2[BO2(OH)].INORGANIC CHEMISTRY,50(11),5098-5104.
MLA Cong, Rihong,et al."Syntheses and Crystal Structures of Two New Bismuth Hydroxyl Borates Containing [Bi2O2](2+) Layers: Bi2O2[B3O5(OH)] and Bi2O2[BO2(OH)]".INORGANIC CHEMISTRY 50.11(2011):5098-5104.
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