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Kinetic Resolution of Hindered Morita-Baylis-Hillman Adducts by Rh(I)-Catalyzed Asymmetric 1,4-Addition/beta-Hydroxyelimination
Wang, Yazhou; Feng, Xiangqing; Du, Haifeng
2011-09-16
Source PublicationORGANIC LETTERS
ISSN1523-7060
Volume13Issue:18Pages:4954-4957
AbstractA kinetic resolution of hindered Morita-Baylis-Hillman adducts has been successfully achieved in excellent selectivities via Rh(1)-catalyzed asymmetric 1,4-addition/beta-hydroxyelimination with the use of a chiral sulfinamide/olefin hybrid ligand. This study provides a novel and efficient access to both optically active hindered highly functionalized alkenes and Morita-Baylis-Hillman adducts.
DOI10.1021/ol202069e
Indexed BySCI ; IC ; CCR
Language英语
WOS IDWOS:000294703900052
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:44[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/73098
Collection中国科学院化学研究所
Corresponding AuthorDu, Haifeng
AffiliationChinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Wang, Yazhou,Feng, Xiangqing,Du, Haifeng. Kinetic Resolution of Hindered Morita-Baylis-Hillman Adducts by Rh(I)-Catalyzed Asymmetric 1,4-Addition/beta-Hydroxyelimination[J]. ORGANIC LETTERS,2011,13(18):4954-4957.
APA Wang, Yazhou,Feng, Xiangqing,&Du, Haifeng.(2011).Kinetic Resolution of Hindered Morita-Baylis-Hillman Adducts by Rh(I)-Catalyzed Asymmetric 1,4-Addition/beta-Hydroxyelimination.ORGANIC LETTERS,13(18),4954-4957.
MLA Wang, Yazhou,et al."Kinetic Resolution of Hindered Morita-Baylis-Hillman Adducts by Rh(I)-Catalyzed Asymmetric 1,4-Addition/beta-Hydroxyelimination".ORGANIC LETTERS 13.18(2011):4954-4957.
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