ICCAS OpenIR
Synthesis, characteristics and photoluminescent properties of novel Ir-Eu heteronuclear complexes containing 2-carboxyl-pyrimidine as a bridging ligand
Lian, Ping1,2; Wei, Huibo1; Zheng, Chen1; Nie, Yifan1; Bian, Jiang1; Bian, Zuqiang1; Huang, Chunhui1
2011
Source PublicationDALTON TRANSACTIONS
ISSN1477-9226
Volume40Issue:20Pages:5476-5482
AbstractTwo novel iridium(III) complexes, [Ir(dfppy)(2)(pmc)] and [Ir(ppy)(2)(pmc)] (dfppy = 2-(4', 6'-difluoro-phenyl) pyridine, ppy = 1-phenyl-pyridine), were designed and synthesized using 2- carboxyl-pyrimidine (Hpmc) as an ancillary ligand. Single crystals were obtained and characterized by single crystal X-ray diffraction. The tetrametallic complexes {[((CN)-N-boolean AND)(2)Ir(mu-pmc)](3)EuCl3} ((CN)-N-boolean AND = dfppy, ppy) were synthesized using the iridium(III) complexes as "ligands". Photophysical and theoretical studies indicate that [Ir(dfppy) 2(pmc)] is more suitable for sensitizing the emission of Eu(III) ions than [Ir(ppy)(2)(pmc)].
DOI10.1039/c0dt01592j
Indexed BySCI
Language英语
WOS IDWOS:000290161900011
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:20[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/73088
Collection中国科学院化学研究所
Corresponding AuthorBian, Zuqiang
Affiliation1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
2.Gannan Normal Univ, Coll Chem & Life Sci, Ganzhou 341000, Jiangxi, Peoples R China
Recommended Citation
GB/T 7714
Lian, Ping,Wei, Huibo,Zheng, Chen,et al. Synthesis, characteristics and photoluminescent properties of novel Ir-Eu heteronuclear complexes containing 2-carboxyl-pyrimidine as a bridging ligand[J]. DALTON TRANSACTIONS,2011,40(20):5476-5482.
APA Lian, Ping.,Wei, Huibo.,Zheng, Chen.,Nie, Yifan.,Bian, Jiang.,...&Huang, Chunhui.(2011).Synthesis, characteristics and photoluminescent properties of novel Ir-Eu heteronuclear complexes containing 2-carboxyl-pyrimidine as a bridging ligand.DALTON TRANSACTIONS,40(20),5476-5482.
MLA Lian, Ping,et al."Synthesis, characteristics and photoluminescent properties of novel Ir-Eu heteronuclear complexes containing 2-carboxyl-pyrimidine as a bridging ligand".DALTON TRANSACTIONS 40.20(2011):5476-5482.
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