ICCAS OpenIR
Self-Assembly of the AB/BC Diblock Copolymer Mixture Based on Hydrogen Bonding in a Selective Solvent: A Monte Carlo Study
Han, Yuanyuan; Jiang, Wei1
2011-03-17
Source PublicationJOURNAL OF PHYSICAL CHEMISTRY B
ISSN1520-6106
Volume115Issue:10Pages:2167-2172
AbstractMonte Carlo simulation was used to study the self-assembly of the AB/BC diblock copolymer mixture based on hydrogen bonding (H-bonding) in a selective solvent. The simulative results indicate that the self-assembled micelle structure is a function of the intensity of the associative interaction (epsilon(hb)) and the directional dependency (P(hb)) of H-bonding, and the intrinsic repulsive interaction (epsilon(AC)) between A and C blocks. The Janus micelles, mixed micelles (micelles with a uniform mixing of different blocks in corona) and pure micelles (micelles with either AB or BC diblock copolymers) are obtained through the adjustment of epsilon(hb) and epsilon(AC). Moreover, the simulative results reveal that decreasing directional dependency (P(hb)) and increasing H-bonding interaction (epsilon(hb)) has an equivalent effect on the micelle structure and H-bonding association for the AB/BC diblock copolymer mixture in a selective solvent.
DOI10.1021/jp1106313
Indexed BySCI
Language英语
WOS IDWOS:000288113300005
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:21[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/72966
Collection中国科学院化学研究所
Corresponding AuthorJiang, Wei
Affiliation1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
2.Chinese Acad Sci, Grad Univ, Changchun 130022, Peoples R China
Recommended Citation
GB/T 7714
Han, Yuanyuan,Jiang, Wei. Self-Assembly of the AB/BC Diblock Copolymer Mixture Based on Hydrogen Bonding in a Selective Solvent: A Monte Carlo Study[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2011,115(10):2167-2172.
APA Han, Yuanyuan,&Jiang, Wei.(2011).Self-Assembly of the AB/BC Diblock Copolymer Mixture Based on Hydrogen Bonding in a Selective Solvent: A Monte Carlo Study.JOURNAL OF PHYSICAL CHEMISTRY B,115(10),2167-2172.
MLA Han, Yuanyuan,et al."Self-Assembly of the AB/BC Diblock Copolymer Mixture Based on Hydrogen Bonding in a Selective Solvent: A Monte Carlo Study".JOURNAL OF PHYSICAL CHEMISTRY B 115.10(2011):2167-2172.
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