Structures of manganese polysulfides: mass-selected photodissociation and density functional calculations

doi:10.1039/c0dt01179g

ICCAS OpenIR

	Structures of manganese polysulfides: mass-selected photodissociation and density functional calculations
	Zhao, Yu-Chao; Yuan, Jinyun; Zhang, Zeng-Guang; Xu, Hong-Guang; Zheng, Weijun
	2011
Source Publication	DALTON TRANSACTIONS
ISSN	1477-9226
Volume	40 Issue:11 Pages:2502-2508
Abstract	Manganese polysulfide cations, MnS(x)(+) (x = 1-10), were studied with mass-selected photodissociation experiments and density functional calculations. We found that MnS(+), MnS(2)(+) and MnS(3)(+) undergo dissociation at 355 nm by loss of S, S(2) and S(3), respectively. The dissociation of larger clusters is relatively complex because of the existence of multiple isomers and multiple dissociation channels. The geometric structures of the low-lying isomers found by theoretical calculations are consistent with the dissociation channels observed in the experiments. The dissociation of MnS(x)(+) clusters occurs mainly by breaking of the Mn-S bonds since they are weaker than the S-S bonds.
DOI	10.1039/c0dt01179g
Indexed By	SCI
Language	英语
WOS ID	WOS:000288030500014
Publisher	ROYAL SOC CHEMISTRY
Citation statistics	Cited Times:12[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.iccas.ac.cn/handle/121111/72932
Collection	中国科学院化学研究所
Corresponding Author	Zheng, Weijun
Affiliation	Chinese Acad Sci, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation GB/T 7714	Zhao, Yu-Chao,Yuan, Jinyun,Zhang, Zeng-Guang,et al. Structures of manganese polysulfides: mass-selected photodissociation and density functional calculations[J]. DALTON TRANSACTIONS,2011,40(11):2502-2508.
APA	Zhao, Yu-Chao,Yuan, Jinyun,Zhang, Zeng-Guang,Xu, Hong-Guang,&Zheng, Weijun.(2011).Structures of manganese polysulfides: mass-selected photodissociation and density functional calculations.DALTON TRANSACTIONS,40(11),2502-2508.
MLA	Zhao, Yu-Chao,et al."Structures of manganese polysulfides: mass-selected photodissociation and density functional calculations".DALTON TRANSACTIONS 40.11(2011):2502-2508.

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