ICCAS OpenIR
Structures of manganese polysulfides: mass-selected photodissociation and density functional calculations
Zhao, Yu-Chao; Yuan, Jinyun; Zhang, Zeng-Guang; Xu, Hong-Guang; Zheng, Weijun
2011
Source PublicationDALTON TRANSACTIONS
ISSN1477-9226
Volume40Issue:11Pages:2502-2508
AbstractManganese polysulfide cations, MnS(x)(+) (x = 1-10), were studied with mass-selected photodissociation experiments and density functional calculations. We found that MnS(+), MnS(2)(+) and MnS(3)(+) undergo dissociation at 355 nm by loss of S, S(2) and S(3), respectively. The dissociation of larger clusters is relatively complex because of the existence of multiple isomers and multiple dissociation channels. The geometric structures of the low-lying isomers found by theoretical calculations are consistent with the dissociation channels observed in the experiments. The dissociation of MnS(x)(+) clusters occurs mainly by breaking of the Mn-S bonds since they are weaker than the S-S bonds.
DOI10.1039/c0dt01179g
Indexed BySCI
Language英语
WOS IDWOS:000288030500014
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/72932
Collection中国科学院化学研究所
Corresponding AuthorZheng, Weijun
AffiliationChinese Acad Sci, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Zhao, Yu-Chao,Yuan, Jinyun,Zhang, Zeng-Guang,et al. Structures of manganese polysulfides: mass-selected photodissociation and density functional calculations[J]. DALTON TRANSACTIONS,2011,40(11):2502-2508.
APA Zhao, Yu-Chao,Yuan, Jinyun,Zhang, Zeng-Guang,Xu, Hong-Guang,&Zheng, Weijun.(2011).Structures of manganese polysulfides: mass-selected photodissociation and density functional calculations.DALTON TRANSACTIONS,40(11),2502-2508.
MLA Zhao, Yu-Chao,et al."Structures of manganese polysulfides: mass-selected photodissociation and density functional calculations".DALTON TRANSACTIONS 40.11(2011):2502-2508.
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