ICCAS OpenIR
Half-titanocenes for precise olefin polymerisation: effects of ligand substituents and some mechanistic aspects
Nomura, Kotohiro1; Liu, Jingyu2
2011-08-01
Source PublicationDALTON TRANSACTIONS
ISSN1477-9226
Volume40Issue:30Pages:7666-7682
AbstractSelected examples concerning effects of both cyclopentadienyl fragment (Cp') and anionic donor ligand (Y) in nonbridged modified half-titanocenes of the type, Cp'TiX(2)(Y) (X = halogen, alkyl), as new type of olefin polymerisation catalysts have been reviewed. These complexes displayed unique characteristics not only for ethylene (co) polymerisation but also for syndiospecific styrene polymerisation, ethylene/styrene copolymerisation; precise fine tuning of the ligand substituents plays an important role for the successful (co) polymerisation; a different mechanistic consideration for the syndiospecific styrene polymerisation, which can explain the copolymerisation behaviour in this catalysis, has also been introduced.
DOI10.1039/c1dt10086f
Indexed BySCI
Language英语
WOS IDWOS:000292972000002
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:69[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/72906
Collection中国科学院化学研究所
Corresponding AuthorNomura, Kotohiro
Affiliation1.Tokyo Metropolitan Univ, Dept Chem, Tokyo 1920397, Japan
2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
Recommended Citation
GB/T 7714
Nomura, Kotohiro,Liu, Jingyu. Half-titanocenes for precise olefin polymerisation: effects of ligand substituents and some mechanistic aspects[J]. DALTON TRANSACTIONS,2011,40(30):7666-7682.
APA Nomura, Kotohiro,&Liu, Jingyu.(2011).Half-titanocenes for precise olefin polymerisation: effects of ligand substituents and some mechanistic aspects.DALTON TRANSACTIONS,40(30),7666-7682.
MLA Nomura, Kotohiro,et al."Half-titanocenes for precise olefin polymerisation: effects of ligand substituents and some mechanistic aspects".DALTON TRANSACTIONS 40.30(2011):7666-7682.
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