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Syntheses and crystal structures of two new aluminoborates with helical channels
Wang, Guo-Ming1; Wang, Pei1; Li, Zeng-Xin1; Huang, Hai-Lan1; Wang, Ying-Xia2; Lin, Jian-Hua2
2011-08-01
Source PublicationSOLID STATE SCIENCES
ISSN1293-2558
Volume13Issue:8Pages:1567-1572
AbstractTwo new aluminoborates, K-2[AlB5O10]center dot(H2O)(4) (1) and [C5H16H2][AlB5O10] (2), have been synthesized under hydrothermal conditions and characterized by elemental analysis, IR, TG analysis, powder and single-crystal X-ray diffractions. Both of the compounds are monoclinic with the lattice constants a = 6.2410(2) angstrom, b = 13.7188(5) angstrom, c = 6.9301(4) angstrom, beta = 95.365(3)degrees and V = 590.75(4) angstrom(3) in the space group P2(1) for 1 and a = 9.0802(3) angstrom, b = 11.1131(2) angstrom, c = 7.9230(5) angstrom, beta = 117.745(3)degrees and V = 707.58(5) in the space group C-2 for 2. These two structures share a similar three-dimensional framework constructed by AlO4 tetrahedra and B5O10 clusters, containing 6, 8-MR helical channels and odd 11-MR channels, in which the guest templates and H2O molecules are located. (C) 2011 Elsevier Masson SAS. All rights reserved.
KeywordBorate Aluminoborate Template Hydrothermal Reaction Porous Material
DOI10.1016/j.solidstatesciences.2011.05.023
Indexed BySCI
Language英语
WOS IDWOS:000294520000020
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/72764
Collection中国科学院化学研究所
Corresponding AuthorWang, Guo-Ming
Affiliation1.Qingdao Univ, Teachers Coll, Coll Chem Chem Engn & Environm, Qingdao 266071, Shandong, Peoples R China
2.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Wang, Guo-Ming,Wang, Pei,Li, Zeng-Xin,et al. Syntheses and crystal structures of two new aluminoborates with helical channels[J]. SOLID STATE SCIENCES,2011,13(8):1567-1572.
APA Wang, Guo-Ming,Wang, Pei,Li, Zeng-Xin,Huang, Hai-Lan,Wang, Ying-Xia,&Lin, Jian-Hua.(2011).Syntheses and crystal structures of two new aluminoborates with helical channels.SOLID STATE SCIENCES,13(8),1567-1572.
MLA Wang, Guo-Ming,et al."Syntheses and crystal structures of two new aluminoborates with helical channels".SOLID STATE SCIENCES 13.8(2011):1567-1572.
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