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Solvent-mediated crystal-to-crystal transformation within the CoBr2 (1,4-dioxane)(m)(H2O)(n) family (m=2, 3; n=0, 2, 4) from 2D to 1D, and 0D
Duan, Zhiming1,2,3; Zhang, Yan4; Zhang, Bin1,2; Zhu, Daoben1,2
2011
Source PublicationCRYSTENGCOMM
ISSN1466-8033
Volume13Issue:22Pages:6801-6810
AbstractA family of coordination compounds: CoBr2(1,4-dioxane)(2) (1), CoBr2(1,4-dioxane)(2)(H2O)(2) (2), CoBr2(1,4-dioxane)(3)(H2O)(4) (3) and CoBr2(1,4-dioxane)(2)(H2O)(4) (4 (C 2/c) and 5 (I 4(1)/a)) with different dimensions have been crystallized from a solution of CH3OH/1,4-dioxane. The solvent-mediated transformation was observed from the blue kinetically favored 2D compound 1 to the red metastable 1D compound 2, 0D compound 3, and finally to the thermodynamically stable 0D compounds 4 and 5. The hydrogen bonds played a key role in the formation of the different networks of 2-5 with the increasing of the coordinated water molecules. The magnetic measurements showed that 1 was a canted antiferromagnet, and 3-5 acted as antiferromagnets.
DOI10.1039/c1ce05668a
Indexed BySCI
Language英语
WOS IDWOS:000296160000033
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:9[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/72630
Collection中国科学院化学研究所
Corresponding AuthorZhang, Bin
Affiliation1.Chinese Acad Sci, Organ Solid Lab, BNLMS, CMS, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
4.Peking Univ, Dept Phys, Inst Condensed Matter & Mat Phys, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Duan, Zhiming,Zhang, Yan,Zhang, Bin,et al. Solvent-mediated crystal-to-crystal transformation within the CoBr2 (1,4-dioxane)(m)(H2O)(n) family (m=2, 3; n=0, 2, 4) from 2D to 1D, and 0D[J]. CRYSTENGCOMM,2011,13(22):6801-6810.
APA Duan, Zhiming,Zhang, Yan,Zhang, Bin,&Zhu, Daoben.(2011).Solvent-mediated crystal-to-crystal transformation within the CoBr2 (1,4-dioxane)(m)(H2O)(n) family (m=2, 3; n=0, 2, 4) from 2D to 1D, and 0D.CRYSTENGCOMM,13(22),6801-6810.
MLA Duan, Zhiming,et al."Solvent-mediated crystal-to-crystal transformation within the CoBr2 (1,4-dioxane)(m)(H2O)(n) family (m=2, 3; n=0, 2, 4) from 2D to 1D, and 0D".CRYSTENGCOMM 13.22(2011):6801-6810.
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