ICCAS OpenIR
Crystal structure and magnetic properties of two dinuclear iron(III) complexes with multidentate Schiff-base ligands
Yan, Lei1; Ding, Shuai1; Ji, Yufei1; Liu, Zhiliang1; Liu, Caiming2
2011
Source PublicationJOURNAL OF COORDINATION CHEMISTRY
ISSN0095-8972
Volume64Issue:20Pages:3531-3540
AbstractTwo dinuclear iron(III) compounds, [Fe(2)(HL(1))(2)(L(1))(2)] center dot MeOH (1) and [Fe(2)(mu-L'(1))(3)] (2) [L(1) N-(2-hydroxypropyl)(3-methoxysalicylaldimine) and L'(1) = 1,2-bis(2-hydroxybenzylidene) hydrazine], have been synthesized and characterized. Structural analysis of 1 shows that the six-coordinate Fe(III)'s are linked by two alkoxo oxygen atoms from two Schiff-base ligands to form a rectangular arrangement of metal ions and oxygen atoms. The distance of these two Fe(III) ions is 3.2122(8) angstrom. In 2, three Schiff-base ligands coordinate two Fe(III) ions in a tetradentate mode; each iron is six coordinate with octahedral geometry. The Fe-Fe distance is 3.9304(10) angstrom. Magnetic susceptibility (2-300 K) indicates an antiferromagnetic interaction between the two oxygen-bridged Fe(III) ions with J = -13.6 cm(-1) for 1.
KeywordDinuclear Iron(Iii) Complexes Schiff-base Ligands Crystal Structure Magnetic Property
DOI10.1080/00958972.2011.625567
Indexed BySCI
Language英语
WOS IDWOS:000299470800009
PublisherTAYLOR & FRANCIS LTD
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/72554
Collection中国科学院化学研究所
Corresponding AuthorLiu, Zhiliang
Affiliation1.Inner Mongolia Univ, Coll Chem & Chem Engn, Hohhot 010021, Peoples R China
2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Lab Organ Solids, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Yan, Lei,Ding, Shuai,Ji, Yufei,et al. Crystal structure and magnetic properties of two dinuclear iron(III) complexes with multidentate Schiff-base ligands[J]. JOURNAL OF COORDINATION CHEMISTRY,2011,64(20):3531-3540.
APA Yan, Lei,Ding, Shuai,Ji, Yufei,Liu, Zhiliang,&Liu, Caiming.(2011).Crystal structure and magnetic properties of two dinuclear iron(III) complexes with multidentate Schiff-base ligands.JOURNAL OF COORDINATION CHEMISTRY,64(20),3531-3540.
MLA Yan, Lei,et al."Crystal structure and magnetic properties of two dinuclear iron(III) complexes with multidentate Schiff-base ligands".JOURNAL OF COORDINATION CHEMISTRY 64.20(2011):3531-3540.
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