ICCAS OpenIR
Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki-Miyaura Coupling Reaction
Ding, San-Yuan1; Gao, Jia1; Wang, Qiong1,2,3; Zhang, Yuan1; Song, Wei-Guo2,3; Su, Cheng-Yong4; Wang, Wei1
2011-12-14
Source PublicationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN0002-7863
Volume133Issue:49Pages:19816-19822
AbstractCovalent organic frameworks (COFs) are crystalline porous solids with well-defined two- or three-dimensional molecular structures. Although the structural regularity provides this new type of porous material with high potentials in catalysis, no example has been presented so far. Herein, we report the first application of a new COF material, COF-LZU1, for highly efficient catalysis. The easily prepared imine-linked COF-LZU1 possesses a two-dimensional eclipsed layered-sheet structure, making its incorporation with metal ions feasible. Via a simple post-treatment, a Pd(II)-containing COF, Pd/COF-LZU1, was accordingly synthesized, which showed excellent catalytic activity in catalyzing the Suzuki-Miyaura coupling reaction. The superior utility of Pd/COF-LZU1 in catalysis was elucidated by the broad scope of the reactants and the excellent yields (96-98%) of the reaction products, together with the high stability and easy recyclability of the catalyst. We expect that our approach will further boost research on designing and employing functional COF materials for catalysis.
DOI10.1021/ja206846p
Indexed BySCI ; CCR
Language英语
WOS IDWOS:000298719800048
PublisherAMER CHEMICAL SOC
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/72512
Collection中国科学院化学研究所
Corresponding AuthorWang, Wei
Affiliation1.Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Gansu, Peoples R China
2.Chinese Acad Sci, Inst Chem, Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Beijing Natl Lab Mol Sci BNLMS, Beijing 100190, Peoples R China
4.Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China
Recommended Citation
GB/T 7714
Ding, San-Yuan,Gao, Jia,Wang, Qiong,et al. Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki-Miyaura Coupling Reaction[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2011,133(49):19816-19822.
APA Ding, San-Yuan.,Gao, Jia.,Wang, Qiong.,Zhang, Yuan.,Song, Wei-Guo.,...&Wang, Wei.(2011).Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki-Miyaura Coupling Reaction.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,133(49),19816-19822.
MLA Ding, San-Yuan,et al."Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki-Miyaura Coupling Reaction".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 133.49(2011):19816-19822.
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