ICCAS OpenIR
Bitriazole bridged manganese(II) framework with weak ferromagnet behavior
Jia, Li-Hui1,2; Liu, An-Chang2; Wang, Bing-Wu1; Wang, Zhe-Ming1; Gao, Song1
2011-11-28
Source PublicationPOLYHEDRON
ISSN0277-5387
Volume30Issue:18Pages:3112-3115
AbstractAn asymmetric bridging ligand 3,4'-bi-1,2,4-triazole (Hbtr) was used for constructing transition metal coordination polymer, and yielding a manganese(II) compound [Mn(btr)(2)](n) (1) with a unique three-dimensional (3D) framework. Single-crystal X-ray diffraction reveals that 1 crystallizes in the orthorhombic space group Fdd2 and the structure is 3D (3, 6)-connected topological framework constructed from manganese ions and mu(3)-btr ligands. The magnetic investigation for compound 1 shows that it is an anti-ferromagnetically coupled 3D array of high-spin manganese(II) ions with long-range ordering below T = 2.6 K, which is a weak ferromagnetic state due to spin-canting. (C) 2011 Elsevier Ltd. All rights reserved.
KeywordCoordination Polymer Manganese Spin Canting Magnetic Properties 3 4 '-bi-1 2 4-triazole
DOI10.1016/j.poly.2011.02.049
Indexed BySCI ; ISTP
Language英语
WOS IDWOS:000298522800028
PublisherPERGAMON-ELSEVIER SCIENCE LTD
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/72492
Collection中国科学院化学研究所
Corresponding AuthorWang, Bing-Wu
Affiliation1.Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
2.Wuhan Inst Chem & Technol, Key Lab Green Chem Proc, Minist Educ, Sch Chem Engn & Pharm, Wuhan 430074, Peoples R China
Recommended Citation
GB/T 7714
Jia, Li-Hui,Liu, An-Chang,Wang, Bing-Wu,et al. Bitriazole bridged manganese(II) framework with weak ferromagnet behavior[J]. POLYHEDRON,2011,30(18):3112-3115.
APA Jia, Li-Hui,Liu, An-Chang,Wang, Bing-Wu,Wang, Zhe-Ming,&Gao, Song.(2011).Bitriazole bridged manganese(II) framework with weak ferromagnet behavior.POLYHEDRON,30(18),3112-3115.
MLA Jia, Li-Hui,et al."Bitriazole bridged manganese(II) framework with weak ferromagnet behavior".POLYHEDRON 30.18(2011):3112-3115.
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