ICCAS OpenIR
Room-Temperature Nickel-Catalysed Suzuki-Miyaura Reactions of Aryl Sulfonates/Halides with Arylboronic Acids
Fan, Xin-Heng1,2; Yang, Lian-Ming1
2011-03-01
Source PublicationEUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN1434-193X
Issue8Pages:1467-1471
AbstractRoom-temperature Suzuki-Miyaura aryl-aryl cross-coupling reactions have been achieved in high yields by using an easily accessible, air-stable Ni(II)-(sigma-aryl) complex as precatalyst without either the pretreatment of organometallic reagents or the presence of external reductants. The Ni(II) complex, in conjunction with monophosphane ligands such as PCy(3)center dot HBF(4) or PPh(3), allowed the efficient cross-coupling of aryl sulfonates (OTs, OMs) and/or halides (Cl, Br, I) with arylboronic acids at room temperature in toluene/water in the presence of K(2)CO(3) as base.
KeywordCross-coupling Nickel Phosphane Ligands Halides Boron
DOI10.1002/ejoc.201001519
Indexed BySCI ; CCR
Language英语
WOS IDWOS:000288129100009
PublisherWILEY-BLACKWELL
Citation statistics
Cited Times:48[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/72478
Collection中国科学院化学研究所
Corresponding AuthorYang, Lian-Ming
Affiliation1.Chinese Acad Sci, Beijing Natl Lab Mol Sci BNLMS, Inst Chem, New Mat Lab, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Fan, Xin-Heng,Yang, Lian-Ming. Room-Temperature Nickel-Catalysed Suzuki-Miyaura Reactions of Aryl Sulfonates/Halides with Arylboronic Acids[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2011(8):1467-1471.
APA Fan, Xin-Heng,&Yang, Lian-Ming.(2011).Room-Temperature Nickel-Catalysed Suzuki-Miyaura Reactions of Aryl Sulfonates/Halides with Arylboronic Acids.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(8),1467-1471.
MLA Fan, Xin-Heng,et al."Room-Temperature Nickel-Catalysed Suzuki-Miyaura Reactions of Aryl Sulfonates/Halides with Arylboronic Acids".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .8(2011):1467-1471.
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