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Iron(III)-Promoted Oxidative Coupling of Naphthylamines: Synthetic and Mechanistic Investigations
Li, Xin-Le1,2; Huang, Jin-Hua1,2; Yang, Lian-Ming1
2011-09-16
Source PublicationORGANIC LETTERS
ISSN1523-7060
Volume13Issue:18Pages:4950-4953
AbstractA facile route to the synthesis of 1,1'-binaphthyl-4,4'-diamines (naphthidines) and 1,1'-binaphthyl-2,2'-diamines (BINAMs) was developed by the oxidative homocoupling of 1- and 2-naphthylamines, respectively, using FeCl(3) as oxidant and K(2)CO(3) as base in 1,2-dichloroethane under ambient conditions. A preliminary mechanistic investigation was performed by the ESR spectroscopy and intermediate-trapping technique.
DOI10.1021/ol202058r
Indexed BySCI ; IC ; CCR
Language英语
WOS IDWOS:000294703900051
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:31[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/72292
Collection中国科学院化学研究所
Corresponding AuthorYang, Lian-Ming
Affiliation1.Chinese Acad Sci, BNLMS, New Mat Lab, Inst Chem, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Li, Xin-Le,Huang, Jin-Hua,Yang, Lian-Ming. Iron(III)-Promoted Oxidative Coupling of Naphthylamines: Synthetic and Mechanistic Investigations[J]. ORGANIC LETTERS,2011,13(18):4950-4953.
APA Li, Xin-Le,Huang, Jin-Hua,&Yang, Lian-Ming.(2011).Iron(III)-Promoted Oxidative Coupling of Naphthylamines: Synthetic and Mechanistic Investigations.ORGANIC LETTERS,13(18),4950-4953.
MLA Li, Xin-Le,et al."Iron(III)-Promoted Oxidative Coupling of Naphthylamines: Synthetic and Mechanistic Investigations".ORGANIC LETTERS 13.18(2011):4950-4953.
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