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Synthesis, Structure and Mimic Catalytic Activity of Novel Vanadium Haloperoxidase Model Complexes
Cao Yun-Zhu1; Li Zhang-Peng1; Xing Yong-Heng1; Wei Dong-Ming1; Pu Zhi-Feng2; Ge Mao-Fa2; Shi Zhan3
2011-05-10
Source PublicationCHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN0251-0790
Volume32Issue:5Pages:1025-1032
AbstractIn order to mimic the active center of the V-HPOs, we designed and synthesized a series of oxovanadium complexes containing poly (pyrazolyl) borate ligands: VO(HB(3,5-Me(2)pz)(3)) (3,5-Me(2)pz) (HOOC-CH2CH2COO) (1) and VO(HB(3,5-Me(2)pz)(3)) (3,5-Me(2)pz) (C5H4N-COO) (2), which were characterized by X-ray single crystal diffraction. Based on the characteristics that vanadium(V) complexes catalyze phenol red oxidation of bromide into bromophenol blue in a water system under weak-acid condition, the study on catalytic activity about scorpionate oxovanadium(IV) complexes was preformed. The result shows that the scorpionate oxovanadium(IV) complexes exhibit catalytic activity to the extent under the similar conditions. The mechanism of the catalytic reaction was analyzed by molecular orbital theory.
KeywordHaloperoxidase Mimic Catalytic Activity Poly(Pyrazolyl) Borate Oxovanadium(Iv) Complex Crystal Structure
Indexed BySCI
Language英语
WOS IDWOS:000291175800008
PublisherHIGHER EDUCATION PRESS
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/72172
Collection中国科学院化学研究所
Corresponding AuthorXing Yong-Heng
Affiliation1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
3.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
Recommended Citation
GB/T 7714
Cao Yun-Zhu,Li Zhang-Peng,Xing Yong-Heng,et al. Synthesis, Structure and Mimic Catalytic Activity of Novel Vanadium Haloperoxidase Model Complexes[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2011,32(5):1025-1032.
APA Cao Yun-Zhu.,Li Zhang-Peng.,Xing Yong-Heng.,Wei Dong-Ming.,Pu Zhi-Feng.,...&Shi Zhan.(2011).Synthesis, Structure and Mimic Catalytic Activity of Novel Vanadium Haloperoxidase Model Complexes.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,32(5),1025-1032.
MLA Cao Yun-Zhu,et al."Synthesis, Structure and Mimic Catalytic Activity of Novel Vanadium Haloperoxidase Model Complexes".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 32.5(2011):1025-1032.
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