ICCAS OpenIR
Comparative study of the optical, electrochemical, electrolumiscent, and photovoltaic properties of dendritic pendants modified poly(p-phenylene vinylene)s
Tan, Zhanao1; Zhang, Wenqing2; Qian, Deping1; Zheng, Hua2; Xiao, Shengqiang2; Li, Yongfang3; Tang, Rupei4; Xi, Fu4
2011-12-01
Source PublicationPOLYMERS FOR ADVANCED TECHNOLOGIES
ISSN1042-7147
Volume22Issue:12Pages:2503-2508
AbstractIn this study, the optical, electrochemical, electrolumiscent, and photovoltaic properties of a series of poly(p-phenylene vinylene) (PPV) derivatives bearing different dendritic pendants, poly{2-[3',5'-bis(2 ''-ethylhexyloxy)benzyloxy]-1,4-phenylenevinylene} (BE-PPV), poly{2-[2',5'-bis(3 '',7 ''-dimethyl)octyloxy]-1,4-phenylenevinylene} (BD-PPV), poly[2-methoxy- 5-(2'-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV), poly{2-[3',5'-bis(2 ''-ethylhexyloxy)benzyloxy]-1,4-phenylenevinylene}-co-poly[2-methoxy-5-(2'-ethylhexyloxy)-1,4-phenylenevinylene] (BE-co-MEH-PPV), and poly{2-[2', 5'-bis(3 '',7 ''-dimethyl)octyloxy]-1,4-phenylenevinylene}-co-poly[2-methoxy-5-(3',7'- dimethyloctyloxy)-1,4-phenylenevinylene] (BD-co-MDMO-PPV), were investigated. The steric pendants strongly affect the absorption spectra, photoluminescence (PL) sepctra, the onset oxidation/reduction potentials, and further affect the electrolumiscent and photovoltaic properties. Copolymerization can reduce the steric effect and improve the electrolumiscent and photovoltaic properties. The brightness of light-emitting diodes base on copolymer BE-co-MEH-PPV and BD-co-MDMO-PPV reached 3988 and 3864 cd/m(2), respectively, much higher than that based on homopolymer BE-PPV (523 cd/m(2)) and BD-PPV (333 cd/m(2)), also higher than that based on MEH-PPV (3788 cd/m(2)). The power conversion efficiency (PCE) of solar cells based on BE-co-MEH-PPV and BD-co-MDMO-PPV reached 1.41, 0.76%, respectively, much higher than that based on BE-PPV (0.24%) and BD-PPV (0.14%). Copyright (C) 2010 John Wiley & Sons, Ltd.
KeywordPoly(P-phenylene Vinylene) (Ppv) Light-emitting Diodes (Leds) Polymer Solar Cells (Pscs)
DOI10.1002/pat.1792
Indexed BySCI
Language英语
WOS IDWOS:000298175400123
PublisherWILEY-BLACKWELL
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/72008
Collection中国科学院化学研究所
Corresponding AuthorTan, Zhanao
Affiliation1.N China Elect Power Univ, Sch Renewable Energy, New & Renewable Energy Beijing Key Lab, Beijing 102206, Peoples R China
2.Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China
3.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing 100190, Peoples R China
4.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Tan, Zhanao,Zhang, Wenqing,Qian, Deping,et al. Comparative study of the optical, electrochemical, electrolumiscent, and photovoltaic properties of dendritic pendants modified poly(p-phenylene vinylene)s[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2011,22(12):2503-2508.
APA Tan, Zhanao.,Zhang, Wenqing.,Qian, Deping.,Zheng, Hua.,Xiao, Shengqiang.,...&Xi, Fu.(2011).Comparative study of the optical, electrochemical, electrolumiscent, and photovoltaic properties of dendritic pendants modified poly(p-phenylene vinylene)s.POLYMERS FOR ADVANCED TECHNOLOGIES,22(12),2503-2508.
MLA Tan, Zhanao,et al."Comparative study of the optical, electrochemical, electrolumiscent, and photovoltaic properties of dendritic pendants modified poly(p-phenylene vinylene)s".POLYMERS FOR ADVANCED TECHNOLOGIES 22.12(2011):2503-2508.
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