Enantioselective Catalysis with Structurally Tunable Immobilized Catalysts
Fan, Qing-Hua1,2; Ding, Kuiling1,2; Ma, SM
AbstractImmobilization of a chiral homogeneous catalyst can in principle facilitate its separation and recycling, and therefore is of considerable interest to both academia and industry. A number of methods have been developed for the immobilization of chiral catalysts, typically including using inert organic or inorganic materials as supports. However, most of the classical immobilized catalysts suffered from inferior catalytic properties to their homogeneous counterparts due to the poor accessibility, random anchoring, or disturbed geometry of the active sites in the solid matrix. In this chapter, we present the progress made in the immobilization of chiral catalysts by focusing on core-functionalized dendrimers in asymmetric catalysis, asymmetric catalysis in nanopores of mesoporous materials, and self-supported chiral catalysts for asymmetric reactions. All the three types of immobilized catalysts possess relatively well-defined structures together with a tunable chiral environment around the catalytically active centers. Representative examples selected from the researches mostly reported by Chinese chemists have demonstrated the high efficiencies and enantioselectivities of these immobilized catalysts. The impacts of supports, such as isolation or confinement effect, on the catalysis will be discussed with emphasis on their application in enantioselective synthesis.
KeywordAsymmetric Catalysis Coordination Polymer Dendrimers Immobilization Nanoporous Solids
Indexed ByBSCI ; SCI
WOS IDWOS:000293254500007
Citation statistics
Cited Times:20[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Corresponding AuthorDing, Kuiling
Affiliation1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China
Recommended Citation
GB/T 7714
Fan, Qing-Hua,Ding, Kuiling,Ma, SM. Enantioselective Catalysis with Structurally Tunable Immobilized Catalysts[J]. ASYMMETRIC CATALYSIS FROM A CHINESE PERSPECTIVE,2011,36:207-245.
APA Fan, Qing-Hua,Ding, Kuiling,&Ma, SM.(2011).Enantioselective Catalysis with Structurally Tunable Immobilized Catalysts.ASYMMETRIC CATALYSIS FROM A CHINESE PERSPECTIVE,36,207-245.
MLA Fan, Qing-Hua,et al."Enantioselective Catalysis with Structurally Tunable Immobilized Catalysts".ASYMMETRIC CATALYSIS FROM A CHINESE PERSPECTIVE 36(2011):207-245.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Fan, Qing-Hua]'s Articles
[Ding, Kuiling]'s Articles
[Ma, SM]'s Articles
Baidu academic
Similar articles in Baidu academic
[Fan, Qing-Hua]'s Articles
[Ding, Kuiling]'s Articles
[Ma, SM]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Fan, Qing-Hua]'s Articles
[Ding, Kuiling]'s Articles
[Ma, SM]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.