ICCAS OpenIR
A highly efficient Co (0) catalyst derived from metal-organic framework for the hydrolysis of ammonia borane
Song, Ping; Li, Yaoqi; Li, Wei; He, Bei; Yang, Junzhi; Li, Xingguo
2011-08-01
Source PublicationINTERNATIONAL JOURNAL OF HYDROGEN ENERGY
ISSN0360-3199
Volume36Issue:17Pages:10468-10473
AbstractA Co (0) catalyst is synthesized by the reduction of a metal-organic framework (MOF) precursor Co(2)(bdc)(2)(dabco) (bdc = 1,4-benzenedicarboxylate; dabco = 1,4-diazabicyclo[2.2.2] octane). The amorphous catalyst exhibits highly efficient activity in the hydrolysis of ammonia borane (AB). The dehydrogenation of a 0.32 M aqueous AB solution completes in 1.4 min under room temperature. The porous structure in the MOF is proposed to play a key role. The catalytic effective Co (0) sites are stabilized by the organic molecules, which used to coordinate to Co (II) in the MOP precursor. This work implies that MOFs, with their large surface area and ample pore structures, may serve as ideal precursors for highly efficient heterogeneous catalysts. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
KeywordMetal-organic Frameworks Heterogeneous Catalyst Ammonia Borane Hydrolysis
DOI10.1016/j.ijhydene.2011.05.120
Indexed BySCI
Language英语
WOS IDWOS:000295235200003
PublisherPERGAMON-ELSEVIER SCIENCE LTD
Citation statistics
Cited Times:43[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/71930
Collection中国科学院化学研究所
Corresponding AuthorLi, Xingguo
AffiliationPeking Univ, BNLMS, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Song, Ping,Li, Yaoqi,Li, Wei,et al. A highly efficient Co (0) catalyst derived from metal-organic framework for the hydrolysis of ammonia borane[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2011,36(17):10468-10473.
APA Song, Ping,Li, Yaoqi,Li, Wei,He, Bei,Yang, Junzhi,&Li, Xingguo.(2011).A highly efficient Co (0) catalyst derived from metal-organic framework for the hydrolysis of ammonia borane.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,36(17),10468-10473.
MLA Song, Ping,et al."A highly efficient Co (0) catalyst derived from metal-organic framework for the hydrolysis of ammonia borane".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 36.17(2011):10468-10473.
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