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Divergent Synthetic Routes for Ring Expansion or Cyclization from 1,4-Allylic Diol Derivatives via Gold(I) Catalysis or Zinc(II) Mediation
Zhu, Li-Li1; Li, Xiao-Xiao1; Zhou, Wen1; Li, Xin1; Chen, Zili1,2
2011-11-04
Source PublicationJOURNAL OF ORGANIC CHEMISTRY
ISSN0022-3263
Volume76Issue:21Pages:8814-8823
AbstractA new efficient method was developed to transform cyclic alkanols into one-carbon higher homologated ketones using various esters as the leaving groups through gold-catalyzed allylic cation-promoted pinacol-type rearrangement. This reaction, coupled with oxy-Cope rearrangement, provided a new strategy to synthesize five-carbon homologated ring ketones. In addition, using ZnBr2, 2,5-dihydrofuran products were obtained in moderate to good yields via an intramolecular cyclization process.
DOI10.1021/jo2015517
Indexed BySCI ; IC ; CCR
Language英语
WOS IDWOS:000296206400023
PublisherAMER CHEMICAL SOC
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Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/71782
Collection中国科学院化学研究所
Corresponding AuthorChen, Zili
Affiliation1.Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China
2.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Zhu, Li-Li,Li, Xiao-Xiao,Zhou, Wen,et al. Divergent Synthetic Routes for Ring Expansion or Cyclization from 1,4-Allylic Diol Derivatives via Gold(I) Catalysis or Zinc(II) Mediation[J]. JOURNAL OF ORGANIC CHEMISTRY,2011,76(21):8814-8823.
APA Zhu, Li-Li,Li, Xiao-Xiao,Zhou, Wen,Li, Xin,&Chen, Zili.(2011).Divergent Synthetic Routes for Ring Expansion or Cyclization from 1,4-Allylic Diol Derivatives via Gold(I) Catalysis or Zinc(II) Mediation.JOURNAL OF ORGANIC CHEMISTRY,76(21),8814-8823.
MLA Zhu, Li-Li,et al."Divergent Synthetic Routes for Ring Expansion or Cyclization from 1,4-Allylic Diol Derivatives via Gold(I) Catalysis or Zinc(II) Mediation".JOURNAL OF ORGANIC CHEMISTRY 76.21(2011):8814-8823.
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