ICCAS OpenIR
Novel 2,7-substituted pyrene derivatives: syntheses, solid-state structures, and properties
Qiao, Yali1,2; Zhang, Jing1,2; Xu, Wei1; Zhu, Daoben1
2011-05-13
Source PublicationTETRAHEDRON
ISSN0040-4020
Volume67Issue:19Pages:3395-3405
AbstractA novel series of pyrene derivatives 3-6 functionalized with different aromatic substituents at 2,7-positions of the pyrene core have been readily synthesized by Suzuki coupling reactions. Single crystals suitable for X-ray crystallographic analysis of compounds 3-6 were all successfully obtained. The optical, electrochemical, and thermal properties of these newly synthesized compounds were thoroughly investigated and discussed. Theoretical calculation was adopted to study the geometric and electronic structure of compounds 3-6. Additionally, preliminary studies demonstrated that field-effect transistors using compound 3, 5, and 6 performed as p-type semiconductors, in which a field-effect mobility as high as 0.018 cm(2) V(-1) s(-1) and current on/off ratio of 10(6) were achieved from compound 6. (C) 2011 Elsevier Ltd. All rights reserved.
KeywordCrystal Structures Density Functional Theoretical Calculation Field-effect Transistors 2 7-substituted Pyrene
DOI10.1016/j.tet.2011.03.055
Indexed BySCI ; IC
Language英语
WOS IDWOS:000290602000014
PublisherPERGAMON-ELSEVIER SCIENCE LTD
Citation statistics
Cited Times:40[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/71696
Collection中国科学院化学研究所
Corresponding AuthorXu, Wei
Affiliation1.Chinese Acad Sci, Inst Chem, Organ Solids Lab, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Qiao, Yali,Zhang, Jing,Xu, Wei,et al. Novel 2,7-substituted pyrene derivatives: syntheses, solid-state structures, and properties[J]. TETRAHEDRON,2011,67(19):3395-3405.
APA Qiao, Yali,Zhang, Jing,Xu, Wei,&Zhu, Daoben.(2011).Novel 2,7-substituted pyrene derivatives: syntheses, solid-state structures, and properties.TETRAHEDRON,67(19),3395-3405.
MLA Qiao, Yali,et al."Novel 2,7-substituted pyrene derivatives: syntheses, solid-state structures, and properties".TETRAHEDRON 67.19(2011):3395-3405.
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