ICCAS OpenIR
Enantioselective Iodolactonizations of (E)- and (Z)-5-Substituted-4-pentenoic Acid Derivatives Mediated by Chiral Salen-Co(II) Complex
Ning Zhao-lun1,2; Ding Jin-ying1; Jin Ri-zhe1; Kang Chuan-qing1; Cheng Yan-qin1; Gao Lian-xun1
2011-01-25
Source PublicationCHEMICAL RESEARCH IN CHINESE UNIVERSITIES
ISSN1005-9040
Volume27Issue:1Pages:45-48
AbstractA number of salen-metal complexes were prepared and their enantioselective catalytic properties toward the asymmetric iodolactonization of (E)- and (Z)-5-substituted-4-pentenoic acid derivatives were investigated. The catalyst system based on salen-Co(II) complex exhibited moderate to good enantioselectivity with the e.e. value ranging from 53% to 74%, as well as high regioselectivity of delta- vs. gamma-iodolactoncs. The salen-Co(11) complex showed the highest enantioselectivity on the asymmetric iodolactonizations of (Z)-5-substituted-4-pentenoic acid derivatives among these reagent-controlled iodolactonization protocols known so far.
KeywordAsymmetric Catalysis Salen-complex Iodolactonization
Indexed BySCI
Language英语
WOS IDWOS:000287825400010
PublisherHIGHER EDUCATION PRESS
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/71660
Collection中国科学院化学研究所
Corresponding AuthorGao Lian-xun
Affiliation1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Ning Zhao-lun,Ding Jin-ying,Jin Ri-zhe,et al. Enantioselective Iodolactonizations of (E)- and (Z)-5-Substituted-4-pentenoic Acid Derivatives Mediated by Chiral Salen-Co(II) Complex[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2011,27(1):45-48.
APA Ning Zhao-lun,Ding Jin-ying,Jin Ri-zhe,Kang Chuan-qing,Cheng Yan-qin,&Gao Lian-xun.(2011).Enantioselective Iodolactonizations of (E)- and (Z)-5-Substituted-4-pentenoic Acid Derivatives Mediated by Chiral Salen-Co(II) Complex.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,27(1),45-48.
MLA Ning Zhao-lun,et al."Enantioselective Iodolactonizations of (E)- and (Z)-5-Substituted-4-pentenoic Acid Derivatives Mediated by Chiral Salen-Co(II) Complex".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 27.1(2011):45-48.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Ning Zhao-lun]'s Articles
[Ding Jin-ying]'s Articles
[Jin Ri-zhe]'s Articles
Baidu academic
Similar articles in Baidu academic
[Ning Zhao-lun]'s Articles
[Ding Jin-ying]'s Articles
[Jin Ri-zhe]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Ning Zhao-lun]'s Articles
[Ding Jin-ying]'s Articles
[Jin Ri-zhe]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.