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Rh-Catalyzed [7+1] Cycloaddition of Buita-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooctadienones
Yao, Zhong-Ke; Li, Jianjun; Yu, Zhi-Xiang1
2011-01-07
Source PublicationORGANIC LETTERS
ISSN1523-7060
Volume13Issue:1Pages:134-137
AbstractDiscovering new carbon building blocks is very significant to advance transition-metal-catalyzed cycloadditions for the synthesis of various-sized ring compounds. A new seven-carbon building block from buta-1,3-dienylcyclopropanes (BDCPs) has been developed, showing that, under the catalysis of [Rh(CO)(2)CO2, BDCPs react with CO to give [7 + 1] cycloaddition products, cyclooctadienones. The present (7 + 1) reaction provides an efficient entry to the synthetically challenging eight-membered carbocyclic skeleton, which is present in many natural products of medicinal and biological significance.
DOI10.1021/ol102700m
Indexed BySCI ; IC ; CCR
Language英语
WOS IDWOS:000285728000035
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:30[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/71586
Collection中国科学院化学研究所
Corresponding AuthorYu, Zhi-Xiang
Affiliation1.Peking Univ, Coll Chem & Mol Engn, Minist Educ, BNLMS, Beijing 100871, Peoples R China
2.Peking Univ, Coll Chem & Mol Engn, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Yao, Zhong-Ke,Li, Jianjun,Yu, Zhi-Xiang. Rh-Catalyzed [7+1] Cycloaddition of Buita-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooctadienones[J]. ORGANIC LETTERS,2011,13(1):134-137.
APA Yao, Zhong-Ke,Li, Jianjun,&Yu, Zhi-Xiang.(2011).Rh-Catalyzed [7+1] Cycloaddition of Buita-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooctadienones.ORGANIC LETTERS,13(1),134-137.
MLA Yao, Zhong-Ke,et al."Rh-Catalyzed [7+1] Cycloaddition of Buita-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooctadienones".ORGANIC LETTERS 13.1(2011):134-137.
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