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Preparation of Melamine-formaldehyde Microspheres and Microcapsules Based on Poly(glutamic acid) by Template Method | |
Zhang Ying1; Yan Shi-Feng1; Rao Shui-Qin1; Zheng Yan-Zhen1; Yin Jing-Bo1; Chen Xue-Si2 | |
2011-10-10 | |
Source Publication | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
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ISSN | 0251-0790 |
Volume | 32Issue:10Pages:2447-2452 |
Abstract | Melamine-formaldehyde (MF) microspheres were prepared by dispersion polymerization. The influences of pH value and reaction time on partical size, surface potential and solubility of MF microspheres were studied. Using MF microspheres as templates, hollow PGA/CS microcapsules were fabricated by layer-by-layer self-assembly technique. The templates and microcapsules were characterized by polarization microscope, nano-granularity and potential analyzer, IR and TEM. The results show that the partical size and surface potential of MF microspheres decrease with the reducing of pH and its solubility in hydrochloric acid becomes worse as the time grows. The main driving force is electrostatic force between PGA and CS, which is supported by alternating zeta potentials. The hollow microcapsules with uniform size and good dispersity shows successful loading of model drug rhodamine, water-soluble drugs. |
Keyword | Melamine-formaldehyde (Mf) Poly (Glutamic Acid) Microcapsule Assembly Technique Zeta-potential |
Indexed By | SCI |
Language | 英语 |
WOS ID | WOS:000296654400040 |
Publisher | HIGHER EDUCATION PRESS |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.iccas.ac.cn/handle/121111/71554 |
Collection | 中国科学院化学研究所 |
Corresponding Author | Yin Jing-Bo |
Affiliation | 1.Shanghai Univ, Dept Polymer Mat, Shanghai 201800, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
Recommended Citation GB/T 7714 | Zhang Ying,Yan Shi-Feng,Rao Shui-Qin,et al. Preparation of Melamine-formaldehyde Microspheres and Microcapsules Based on Poly(glutamic acid) by Template Method[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2011,32(10):2447-2452. |
APA | Zhang Ying,Yan Shi-Feng,Rao Shui-Qin,Zheng Yan-Zhen,Yin Jing-Bo,&Chen Xue-Si.(2011).Preparation of Melamine-formaldehyde Microspheres and Microcapsules Based on Poly(glutamic acid) by Template Method.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,32(10),2447-2452. |
MLA | Zhang Ying,et al."Preparation of Melamine-formaldehyde Microspheres and Microcapsules Based on Poly(glutamic acid) by Template Method".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 32.10(2011):2447-2452. |
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