ICCAS OpenIR
Asymmetric Tandem Reduction of 2-(Aroylmethyl)quinolines with Phosphine-Free Ru-TsDPEN Catalyst
Wang, Tianli; Ouyang, Guanghui; He, Yan-Mei; Fan, Qing-Hua1
2011-04-01
Source PublicationSYNLETT
ISSN0936-5214
Issue7Pages:939-942
AbstractThe phosphine-free ruthenium complex containing chiral N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine (TsDPEN) showed excellent stereoselectivity in the tandem asymmetric reduction of 2-(aroylmethyl)quinolines. The reaction involves transfer hydrogenation of aromatic ketones and hydrogenation of quinolines, giving 1,2,3,4-tetrahydroquinoline derivatives with up to 99% ee and 95:5 dr.
KeywordAsymmetric Catalysis Tandem Reaction Quinolines Ruthenium Hydrogenation
DOI10.1055/s-0030-1259905
Indexed BySCI ; IC ; CCR
Language英语
WOS IDWOS:000289411900016
PublisherGEORG THIEME VERLAG KG
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/71508
Collection中国科学院化学研究所
Corresponding AuthorFan, Qing-Hua
Affiliation1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Wang, Tianli,Ouyang, Guanghui,He, Yan-Mei,et al. Asymmetric Tandem Reduction of 2-(Aroylmethyl)quinolines with Phosphine-Free Ru-TsDPEN Catalyst[J]. SYNLETT,2011(7):939-942.
APA Wang, Tianli,Ouyang, Guanghui,He, Yan-Mei,&Fan, Qing-Hua.(2011).Asymmetric Tandem Reduction of 2-(Aroylmethyl)quinolines with Phosphine-Free Ru-TsDPEN Catalyst.SYNLETT(7),939-942.
MLA Wang, Tianli,et al."Asymmetric Tandem Reduction of 2-(Aroylmethyl)quinolines with Phosphine-Free Ru-TsDPEN Catalyst".SYNLETT .7(2011):939-942.
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