ICCAS OpenIR
Formation of Zirconocenes Containing Vinyl-imine and Keteniminate Species from Zirconacycles and Diphenylacetonitrile
Zhao, Jing2; Zhang, Shaoguang1; Zhang, Wen-Xiong1; Xi, Zhenfeng1,3
2011-07-11
Source PublicationORGANOMETALLICS
ISSN0276-7333
Volume30Issue:13Pages:3464-3467
AbstractThe first well-defined zirconocene complexes processing vinyl-imine and keteniminate species have been achieved from zirconacyclopentenes or zirconacyclopentadienes and 2 equiv of Ph2CHCN. Multifunctional effect of Ph2CHCN is observed for the first time in one system. This process proceeds via the azazirconacyclopentadiene intermediate and its intramolecular proton transfer. Moreover, beta,beta'-C-C bond cleavage of tetra-alkyl-substituted zirconacyclopentadienes is observed for the first time under the appropriate conditions.
DOI10.1021/om200404p
Indexed BySCI ; IC ; CCR
Language英语
WOS IDWOS:000292417900005
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:24[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/71496
Collection中国科学院化学研究所
Corresponding AuthorZhang, Wen-Xiong
Affiliation1.Peking Univ, Coll Chem, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
Recommended Citation
GB/T 7714
Zhao, Jing,Zhang, Shaoguang,Zhang, Wen-Xiong,et al. Formation of Zirconocenes Containing Vinyl-imine and Keteniminate Species from Zirconacycles and Diphenylacetonitrile[J]. ORGANOMETALLICS,2011,30(13):3464-3467.
APA Zhao, Jing,Zhang, Shaoguang,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2011).Formation of Zirconocenes Containing Vinyl-imine and Keteniminate Species from Zirconacycles and Diphenylacetonitrile.ORGANOMETALLICS,30(13),3464-3467.
MLA Zhao, Jing,et al."Formation of Zirconocenes Containing Vinyl-imine and Keteniminate Species from Zirconacycles and Diphenylacetonitrile".ORGANOMETALLICS 30.13(2011):3464-3467.
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