ICCAS OpenIR
Kinetics of the gas-phase reactions of some unsaturated alcohols with Cl atoms and O-3
Gai, Yanbo1,2; Ge, Maofa1; Wang, Weigang1
2011
Source PublicationATMOSPHERIC ENVIRONMENT
ISSN1352-2310
Volume45Issue:1Pages:53-59
AbstractReactions of Cl atoms with 3-buten-1-ol, 3-methyl-3-buten-1-ol, 2-methyl-3-buten-1-ol and 4-penten-2-ol were investigated using relative technique with gas chromatograph coupled with flame ionization detection (GC-FID). At 298 +/- 1 K and 1.01 x 10(5) Pa, the rate coefficients measured (in units of 10(-10) cm(3) molecule-(1) s(-1)) were 3.63 +/- 0.49, 4.13 +/- 0.56, 3.51 +/- 0.48, and 3.62 +/- 0.49, respectively. The quoted errors included 2 sigma from the least-squares analysis and also 10% errors caused by the uncertainty of the reference rate coefficients. In addition, rate coefficients for reactions of the unsaturated alcohols with O-3 were determined using absolute method. The values obtained have been presented, compared with those of their alkene structural homologues and discussed. Reactivity trends and atmospheric implications have also been discussed. (C) 2010 Elsevier Ltd. All rights reserved.
KeywordCl Atoms Ozone Rate Coefficient Unsaturated Alcohols
DOI10.1016/j.atmosenv.2010.09.047
Indexed BySCI
Language英语
WOS IDWOS:000285675600005
PublisherPERGAMON-ELSEVIER SCIENCE LTD
Citation statistics
Cited Times:16[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/71416
Collection中国科学院化学研究所
Corresponding AuthorGe, Maofa
Affiliation1.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, BNLMS, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Gai, Yanbo,Ge, Maofa,Wang, Weigang. Kinetics of the gas-phase reactions of some unsaturated alcohols with Cl atoms and O-3[J]. ATMOSPHERIC ENVIRONMENT,2011,45(1):53-59.
APA Gai, Yanbo,Ge, Maofa,&Wang, Weigang.(2011).Kinetics of the gas-phase reactions of some unsaturated alcohols with Cl atoms and O-3.ATMOSPHERIC ENVIRONMENT,45(1),53-59.
MLA Gai, Yanbo,et al."Kinetics of the gas-phase reactions of some unsaturated alcohols with Cl atoms and O-3".ATMOSPHERIC ENVIRONMENT 45.1(2011):53-59.
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