ICCAS OpenIR
Planar Quinary Cluster inside a Fullerene Cage: Synthesis and Structural Characterizations of Sc3NC@C-80-I-h
Wang, Tai-Shan3; Feng, Lai3; Wu, Jing-Yi3; Xu, Wei3; Xiang, Jun-Feng3; Tan, Kai1,2; Ma, Yi-Han3; Zheng, Jun-Peng3; Jiang, Li3; Lu, Xin1,2; Shu, Chun-Ying3; Wang, Chun-Ru3
2010-11-24
Source PublicationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN0002-7863
Volume132Issue:46Pages:16362-16364
AbstractThe endohedral fullerene Sc3NC@C-80-I-h has been synthesized and characterized; it has an unprecedented planar quinary cluster in a fullerene cage. It is also the first chemical compound in which the presence of an unprecedented (NC)(3-) trianion has been disclosed. The fascinating intramolecular dynamics in Sc3NC@C-80-I-h enables the whole molecule to display high polarity and promising ferroelectricity. This finding inspires the possibility that such a planar quinary cluster may be useful in constructing many other endohedral fullerenes.
DOI10.1021/ja107843b
Indexed BySCI
Language英语
WOS IDWOS:000284792000022
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:94[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/71216
Collection中国科学院化学研究所
Corresponding AuthorLu, Xin
Affiliation1.Xiamen Univ, State Key Lab Phys Chem Solid Surface, Xiamen 361005, Peoples R China
2.Xiamen Univ, Ctr Theoret Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China
3.Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Wang, Tai-Shan,Feng, Lai,Wu, Jing-Yi,et al. Planar Quinary Cluster inside a Fullerene Cage: Synthesis and Structural Characterizations of Sc3NC@C-80-I-h[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2010,132(46):16362-16364.
APA Wang, Tai-Shan.,Feng, Lai.,Wu, Jing-Yi.,Xu, Wei.,Xiang, Jun-Feng.,...&Wang, Chun-Ru.(2010).Planar Quinary Cluster inside a Fullerene Cage: Synthesis and Structural Characterizations of Sc3NC@C-80-I-h.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,132(46),16362-16364.
MLA Wang, Tai-Shan,et al."Planar Quinary Cluster inside a Fullerene Cage: Synthesis and Structural Characterizations of Sc3NC@C-80-I-h".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 132.46(2010):16362-16364.
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