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Asymmetric Michael Addition Reaction of 3-Substituted Oxindoles to Nitroolefins Catalyzed by a Chiral Alkyl-Substituted Thiourea Catalyst
Li, Xin1; Zhang, Bo2,3; Xi, Zhi-Guo2,3; Luo, Sanzhong1; Cheng, Jin-Pei1,2,3
2010-02-01
Source PublicationADVANCED SYNTHESIS & CATALYSIS
ISSN1615-4150
Volume352Issue:2-3Pages:416-424
AbstractA simple alkylthiourea was found to be an effective catalyst for the Michael addition reaction of 3-substituted oxindole to nitroolefins. A number of 3,3'-substituted oxindole derivatives, which have two vicinal quaternary-tertiary chiral centers were synthesized with up to 99% yields 19:1 dr and 98% ee.
KeywordBifunctional Thioureas Michael Addition Reaction Nitroolefins Organocatalysis Oxindoles
DOI10.1002/adsc.200900630
Indexed BySCI ; IC
Language英语
WOS IDWOS:000275235800024
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:99[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/71150
Collection中国科学院化学研究所
Corresponding AuthorLuo, Sanzhong
Affiliation1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, BNLMS, Beijing 100190, Peoples R China
2.Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
3.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
Recommended Citation
GB/T 7714
Li, Xin,Zhang, Bo,Xi, Zhi-Guo,et al. Asymmetric Michael Addition Reaction of 3-Substituted Oxindoles to Nitroolefins Catalyzed by a Chiral Alkyl-Substituted Thiourea Catalyst[J]. ADVANCED SYNTHESIS & CATALYSIS,2010,352(2-3):416-424.
APA Li, Xin,Zhang, Bo,Xi, Zhi-Guo,Luo, Sanzhong,&Cheng, Jin-Pei.(2010).Asymmetric Michael Addition Reaction of 3-Substituted Oxindoles to Nitroolefins Catalyzed by a Chiral Alkyl-Substituted Thiourea Catalyst.ADVANCED SYNTHESIS & CATALYSIS,352(2-3),416-424.
MLA Li, Xin,et al."Asymmetric Michael Addition Reaction of 3-Substituted Oxindoles to Nitroolefins Catalyzed by a Chiral Alkyl-Substituted Thiourea Catalyst".ADVANCED SYNTHESIS & CATALYSIS 352.2-3(2010):416-424.
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