ICCAS OpenIR
Synthesis and Ethylene Polymerization by beta-Diketiminato Zirconium Chlorides
Yuan, Shifang1,2,3; Zhang, Liping1,2,3; Liu, Diansheng1; Sun, Wen-Hua2,3
2010-07-01
Source PublicationMACROMOLECULAR RESEARCH
ISSN1598-5032
Volume18Issue:7Pages:690-694
AbstractUnsymmetrical beta-diketiminato zirconium chlorides were prepared by an elimination reaction of ZrCl(4) with the corresponding beta-diketiminato lithium atoms [Li{N(Dipp)C(R)CHC((t)Bu)NH}](2) (Dipp=2,6-(i)Pr(2)C(6)H(3); R=Ph or Me). Two zirconium complexes were fully characterized by elemental, (1)H, and (13)C NMR analyses, and confirmed by single-crystal X-ray diffraction. These complexes, activated with methylaluminoxane (MAO) showed good activity towards ethylene polymerization, and produced high molecular weight polyethylene.
KeywordBeta-diketiminate Zirconium Ethylene Polymerization Molecular Weight Polyethylene
DOI10.1007/s13233-010-0704-9
Indexed BySCI
Language英语
WOS IDWOS:000282470900012
PublisherSPRINGER
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/70998
Collection中国科学院化学研究所
Corresponding AuthorLiu, Diansheng
Affiliation1.Shanxi Univ, Inst Appl Chem, Taiyuan 030006, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Yuan, Shifang,Zhang, Liping,Liu, Diansheng,et al. Synthesis and Ethylene Polymerization by beta-Diketiminato Zirconium Chlorides[J]. MACROMOLECULAR RESEARCH,2010,18(7):690-694.
APA Yuan, Shifang,Zhang, Liping,Liu, Diansheng,&Sun, Wen-Hua.(2010).Synthesis and Ethylene Polymerization by beta-Diketiminato Zirconium Chlorides.MACROMOLECULAR RESEARCH,18(7),690-694.
MLA Yuan, Shifang,et al."Synthesis and Ethylene Polymerization by beta-Diketiminato Zirconium Chlorides".MACROMOLECULAR RESEARCH 18.7(2010):690-694.
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