ICCAS OpenIR
PROSPECTS AND CRUCIAL PROBLEMS IN OLIGOMERIZATION AND POLYMERIZATION WITH IRON AND COBALT COMPLEX CATALYSTS
Jie, Su-yun3; Sun, Wen-hua1,2; Xiao, Tianpengfei1,2
2010-05-01
Source PublicationCHINESE JOURNAL OF POLYMER SCIENCE
ISSN0256-7679
Volume28Issue:3Pages:299-304
AbstractThe discovery of highly active 2,6-bis(imino)pyridyl iron and cobalt complexes provided a milestone of late-transition metal catalysts for ethylene oligomerization and polymerization with being currently investigated for the scale-up process. The crucial problems are remaining in the catalytic systems: the catalytic systems targeting ethylene polymerization produce more oligomers at elevated reaction temperatures, however, there is a recognizable amount of high-molecular-weight polyethylene remained in the modified catalytic system for the oligomerization process. Beyond the modification of bis(imino)pyridyl metal complexes, several alternative procatalysts' models have been developed in our group. This review highlighted the achievements in exploring new iron and cobalt complexes with tridentate NNN ligands as procatalysts for ethylene oligomerization and polymerization.
KeywordIron Complex Cobalt Complex Ethylene Oligomerization Ethylene Polymerization
DOI10.1007/s10118-010-0034-6
Indexed BySCI
Language英语
WOS IDWOS:000279111400002
PublisherSPRINGER
Citation statistics
Cited Times:46[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/70996
Collection中国科学院化学研究所
Corresponding AuthorSun, Wen-hua
Affiliation1.Chinese Acad Sci, Key Lab Engn Plast, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China
3.Zhejiang Univ, State Key Lab Chem Engn, Dept Chem & Biol Engn, Hangzhou 310027, Zhejiang, Peoples R China
Recommended Citation
GB/T 7714
Jie, Su-yun,Sun, Wen-hua,Xiao, Tianpengfei. PROSPECTS AND CRUCIAL PROBLEMS IN OLIGOMERIZATION AND POLYMERIZATION WITH IRON AND COBALT COMPLEX CATALYSTS[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2010,28(3):299-304.
APA Jie, Su-yun,Sun, Wen-hua,&Xiao, Tianpengfei.(2010).PROSPECTS AND CRUCIAL PROBLEMS IN OLIGOMERIZATION AND POLYMERIZATION WITH IRON AND COBALT COMPLEX CATALYSTS.CHINESE JOURNAL OF POLYMER SCIENCE,28(3),299-304.
MLA Jie, Su-yun,et al."PROSPECTS AND CRUCIAL PROBLEMS IN OLIGOMERIZATION AND POLYMERIZATION WITH IRON AND COBALT COMPLEX CATALYSTS".CHINESE JOURNAL OF POLYMER SCIENCE 28.3(2010):299-304.
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