ICCAS OpenIR
New Second-Order Nonlinear Optical Polymers Derived from AB(2) and AB Monomers via Sonogashira Coupling Reaction
Li, Zhong'an1; Wu, Wenbo1; Ye, Cheng2; Qin, Jingui1; Li, Zhen1
2010-04-15
Source PublicationMACROMOLECULAR CHEMISTRY AND PHYSICS
ISSN1022-1352
Volume211Issue:8Pages:916-923
AbstractIn this paper, a facile route was designed to prepare a new AB(2)-type polymer P1 via simple Sonogashira coupling reaction, also its corresponding linear analog (P2) was obtained from AB monomer for comparison. Despite the relatively lower loading density of the effective chromophore moieties, P1 demonstrated higher second-harmonic coefficient (153.9 pm . V-1) than that of P2 (98.2 pm . V-1), due to the three-dimensional spatial isolation effect of the hyperbranched structure. The good results of P2 also indicated that the ladder shape may help to solve the problem existing in main-chain polymers, the low poling efficiency.
KeywordHyperbranched Polymer Monomers Nonlinear Optics Sonogashira Coupling Reaction Synthesis
DOI10.1002/macp.200900605
Indexed BySCI ; IC
Language英语
WOS IDWOS:000277354500009
PublisherWILEY-BLACKWELL
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/70984
Collection中国科学院化学研究所
Corresponding AuthorLi, Zhen
Affiliation1.Wuhan Univ, Dept Chem, Hubei Key Lab Organ & Polymer Optoelect Mat, Wuhan 430072, Peoples R China
2.Chinese Acad Sci, Inst Chem, Organ Solids Labs, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Li, Zhong'an,Wu, Wenbo,Ye, Cheng,et al. New Second-Order Nonlinear Optical Polymers Derived from AB(2) and AB Monomers via Sonogashira Coupling Reaction[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS,2010,211(8):916-923.
APA Li, Zhong'an,Wu, Wenbo,Ye, Cheng,Qin, Jingui,&Li, Zhen.(2010).New Second-Order Nonlinear Optical Polymers Derived from AB(2) and AB Monomers via Sonogashira Coupling Reaction.MACROMOLECULAR CHEMISTRY AND PHYSICS,211(8),916-923.
MLA Li, Zhong'an,et al."New Second-Order Nonlinear Optical Polymers Derived from AB(2) and AB Monomers via Sonogashira Coupling Reaction".MACROMOLECULAR CHEMISTRY AND PHYSICS 211.8(2010):916-923.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Li, Zhong'an]'s Articles
[Wu, Wenbo]'s Articles
[Ye, Cheng]'s Articles
Baidu academic
Similar articles in Baidu academic
[Li, Zhong'an]'s Articles
[Wu, Wenbo]'s Articles
[Ye, Cheng]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Li, Zhong'an]'s Articles
[Wu, Wenbo]'s Articles
[Ye, Cheng]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.