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Synthesis, Structure and Properties of Tren-Schiff Base Compound and Its Manganese(III) Complex by Original Self-assembly Reaction
Zhao Hai-yan1; Li Jing1; Xing Yong-heng1; Pu Zhi-feng2; Bai Feng-ying1; Ge Mao-fa2; Niu Shu-yun1
2010-09-25
Source PublicationCHEMICAL RESEARCH IN CHINESE UNIVERSITIES
ISSN1005-9040
Volume26Issue:5Pages:687-692
AbstractThe new self-assembly tripodal hexadentate Schiff base compound, C27H30N4O3, derived from tris(2-aminoethyl)amine(tren) with salicylaldehyde and its manganese(III) complex [(C27H27N4O3)Mn]center dot CH3OH(1) were designed and synthesized by original self-assembly reaction at room temperature in the solution of methanol. Both the compounds were characterized by elemental analysis, IR spectrometry, UV-Vis spectroscopy and X-ray single crystal diffraction. It is noteworthy that the tripodal hexadentate Schiff base ligand effectively encapsulates the manganese(III) ion and enforces a six-coordinate geometry in complex 1 with the apical nitrogen atom of tren-Schiff base remaining unbound to the metal. It is found that there are several intra-molecular hydrogen bonds in them(C-H center dot center dot center dot O and O-H center dot center dot center dot N). In addition, quantum chemistry calculations were also performed and discussed in detail. These results are consistent with the structural analyses of them.
KeywordTren-schiff Base Crystal Structure Hydrogen Bond Quantum Chemistry
Indexed BySCI
Language英语
WOS IDWOS:000283618500004
PublisherHIGHER EDUCATION PRESS
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/70708
Collection中国科学院化学研究所
Corresponding AuthorXing Yong-heng
Affiliation1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Zhao Hai-yan,Li Jing,Xing Yong-heng,et al. Synthesis, Structure and Properties of Tren-Schiff Base Compound and Its Manganese(III) Complex by Original Self-assembly Reaction[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2010,26(5):687-692.
APA Zhao Hai-yan.,Li Jing.,Xing Yong-heng.,Pu Zhi-feng.,Bai Feng-ying.,...&Niu Shu-yun.(2010).Synthesis, Structure and Properties of Tren-Schiff Base Compound and Its Manganese(III) Complex by Original Self-assembly Reaction.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,26(5),687-692.
MLA Zhao Hai-yan,et al."Synthesis, Structure and Properties of Tren-Schiff Base Compound and Its Manganese(III) Complex by Original Self-assembly Reaction".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 26.5(2010):687-692.
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