Catalytic Organic Reactions in CO2/H2O Medium
Wu Suxiang; Fan Honglei; Cheng Yan; Wang Qian; Han Buxing
AbstractGreen chemistry is the trend of chemistry in the future. Utilization of green solvents effectively is one of the, important topics in green chemistry. CO2/H2O system is green reaction medium with some unique features, and can be used in different chemical reactions. Especially, it can be used in the reactions catalyzed by weak acids, in which the use of conventional hazardous acids can be avoided. In this review, we first discuss the variation of the acidity of CO2/H2O system with temperature and pressure, then some chemical reactions in CO2/H2O system are discussed, including dehydration reaction, alkylation reaction, citronellal cyclization reaction, diazonium reaction, conversion of polyalcohol to cyclic ether, oxybromination reaction, selective reduction of nitroarenes, polysaccharide hydrolysis, conversion of biomass, hydrolysis of propylene oxide, decarboxylation reaction, oxidation of alcohols, enantioselective sulfoxidation, asymmetric reduction of ketones. Finally, the future directions for the applications of CO2/H2O system in chemical reactions are discussed briefly.
KeywordGreen Chemistry Mixed Green Solvents Co2 H2o Catalysis Organic Reaction
Indexed BySCI
WOS IDWOS:000280274000005
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Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Corresponding AuthorHan Buxing
AffiliationChinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Wu Suxiang,Fan Honglei,Cheng Yan,et al. Catalytic Organic Reactions in CO2/H2O Medium[J]. PROGRESS IN CHEMISTRY,2010,22(7):1286-1294.
APA Wu Suxiang,Fan Honglei,Cheng Yan,Wang Qian,&Han Buxing.(2010).Catalytic Organic Reactions in CO2/H2O Medium.PROGRESS IN CHEMISTRY,22(7),1286-1294.
MLA Wu Suxiang,et al."Catalytic Organic Reactions in CO2/H2O Medium".PROGRESS IN CHEMISTRY 22.7(2010):1286-1294.
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