ICCAS OpenIR
An Unprecedented Silver Salt Effect Switches the Facial Selectivity in the Vinylogous Mukaiyama Aldol Reaction
Liang, Yufan2,3,4; Wang, Lin2,3,4; Zhu, Rong2,3,4; Deng, Lujiang2,3,4; Yang, Yunfang1; Quan, Junmin1; Chen, Jiahua2,3,4; Yang, Zhen1,2,3,4
2010-10-04
Source PublicationADVANCED SYNTHESIS & CATALYSIS
ISSN1615-4150
Volume352Issue:14-15Pages:2387-2393
AbstractSilver hexafluroantimonate was identified as a highly efficient agent to reverse the facial selectivity of the titanium chloride-mediated vinylogous Mukaiyama aldol reaction (VMAR), and this unprecedented reaction provides a concise, diastereoselective synthesis of delta-hydroxy-alpha,gamma-dimethyl-alpha,beta-unsaturated carbonyl units from readily available chiral vinylketene silyl N,O-acetal 6 and ethyl glyoxylate 8.
KeywordEthyl Glyoxylate Silver Hexafluroantimonate Titanium Chloride-mediated Reaction Vinylogous Mukaiyama Aldol Reaction Chiral Vinylketene Silyl n O-acetals
DOI10.1002/adsc.201000420
Indexed BySCI ; IC ; CCR
Language英语
WOS IDWOS:000284003100007
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/70570
Collection中国科学院化学研究所
Corresponding AuthorQuan, Junmin
Affiliation1.Peking Univ, Shenzhen Grad Sch, Sch Chem Biol & Biotechnol, Lab Chem Genom, Shenzhen 518055, Peoples R China
2.Peking Univ, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China
3.Peking Univ, BNLMS, Coll Chem, Beijing 100871, Peoples R China
4.Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Liang, Yufan,Wang, Lin,Zhu, Rong,et al. An Unprecedented Silver Salt Effect Switches the Facial Selectivity in the Vinylogous Mukaiyama Aldol Reaction[J]. ADVANCED SYNTHESIS & CATALYSIS,2010,352(14-15):2387-2393.
APA Liang, Yufan.,Wang, Lin.,Zhu, Rong.,Deng, Lujiang.,Yang, Yunfang.,...&Yang, Zhen.(2010).An Unprecedented Silver Salt Effect Switches the Facial Selectivity in the Vinylogous Mukaiyama Aldol Reaction.ADVANCED SYNTHESIS & CATALYSIS,352(14-15),2387-2393.
MLA Liang, Yufan,et al."An Unprecedented Silver Salt Effect Switches the Facial Selectivity in the Vinylogous Mukaiyama Aldol Reaction".ADVANCED SYNTHESIS & CATALYSIS 352.14-15(2010):2387-2393.
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