ICCAS OpenIR
Sensitized luminescence from lanthanides in d-f bimetallic complexes
Chen, Fang-Fang; Chen, Zhu-Qi; Bian, Zu-Qiang; Huang, Chun-Hui
2010-05-01
Source PublicationCOORDINATION CHEMISTRY REVIEWS
ISSN0010-8545
Volume254Issue:9-10Pages:991-1010
AbstractThis article reviews progress in the research of transition metal-lanthanide (d-f) bimetallic complexes Through efficient energy transfer, sensitized luminescence of lanthanide ions from the visible range (Eu(III)) to the near-infrared region (Nd(III), Yb(III), Er(III) and Pr(III)) is obtained in these bimetallic assembles The d-block in d-f bimetallic complexes mainly contributes to the improvement of lanthanide emission efficiency and the extension of the excitation window for the lanthanide complexes. Examples are catalogued by various transition metals, such as Ru(II), Os(II) (Fe(II)), Pt(II) (Au(I)), Pd(II), Cr(III), Co(III), Zn(II) and Ir(III). The relevant synthetic procedures, crystal structures and photophysical properties of these d-f complexes are briefly described Additionally, the molecular properties responsible for the performance of certain d-f systems, such as energy levels, nuclear distances and coordination environments, will be discussed (C) 2009 Elsevier B.V. All rights reserved.
KeywordBimetallic Complexes Transition Metals Lanthanides Red Emission Nir Emission
DOI10.1016/j.ccr.2009.12.028
Indexed BySCI
Language英语
WOS IDWOS:000276380800005
PublisherELSEVIER SCIENCE SA
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/70456
Collection中国科学院化学研究所
Corresponding AuthorHuang, Chun-Hui
AffiliationPeking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Chen, Fang-Fang,Chen, Zhu-Qi,Bian, Zu-Qiang,et al. Sensitized luminescence from lanthanides in d-f bimetallic complexes[J]. COORDINATION CHEMISTRY REVIEWS,2010,254(9-10):991-1010.
APA Chen, Fang-Fang,Chen, Zhu-Qi,Bian, Zu-Qiang,&Huang, Chun-Hui.(2010).Sensitized luminescence from lanthanides in d-f bimetallic complexes.COORDINATION CHEMISTRY REVIEWS,254(9-10),991-1010.
MLA Chen, Fang-Fang,et al."Sensitized luminescence from lanthanides in d-f bimetallic complexes".COORDINATION CHEMISTRY REVIEWS 254.9-10(2010):991-1010.
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