ICCAS OpenIR
Effect of conformational asymmetry on the self-assembly of amphiphilic diblock copolymer in selective solvent
Li, Wei1,2; Jiang, Wei1,2
2010-05-01
Source PublicationPOLYMER BULLETIN
ISSN0170-0839
Volume64Issue:8Pages:805-815
AbstractThree dimensional real-space self-consistent field theory is employed to study the effect of conformational asymmetry on the self-assembly of amphiphilic diblock copolymer in selective solvent. The phase diagrams in wide ranges of interaction parameters and conformational asymmetry were obtained in present study. The results indicate that the conformational asymmetry is an important factor that determines the self-assembly of amphiphilic diblock copolymer in solution. The self-assembled morphology changes from sphere to rod, then to vesicle with an increase of the degree of conformational asymmetry. We found that the entropic contribution of the core-forming block is the main reason for this transition.
KeywordConformational Asymmetry Diblock Copolymer Self-assembly Selectivity Self-consistent Field Theory
DOI10.1007/s00289-010-0265-2
Indexed BySCI
Language英语
WOS IDWOS:000276440300007
PublisherSPRINGER
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/70418
Collection中国科学院化学研究所
Corresponding AuthorJiang, Wei
Affiliation1.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Changchun Inst Appl Chem, Changchun 130022, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing, Peoples R China
Recommended Citation
GB/T 7714
Li, Wei,Jiang, Wei. Effect of conformational asymmetry on the self-assembly of amphiphilic diblock copolymer in selective solvent[J]. POLYMER BULLETIN,2010,64(8):805-815.
APA Li, Wei,&Jiang, Wei.(2010).Effect of conformational asymmetry on the self-assembly of amphiphilic diblock copolymer in selective solvent.POLYMER BULLETIN,64(8),805-815.
MLA Li, Wei,et al."Effect of conformational asymmetry on the self-assembly of amphiphilic diblock copolymer in selective solvent".POLYMER BULLETIN 64.8(2010):805-815.
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