ICCAS OpenIR
Synthesis and Physical Properties of Red Emitting Materials Based on Porphyrin Derivatives
Wan Zhongquan1; Jia Chunyang1; Zhang Jiaqiang1; Zhang Guanxin2
2010-11-14
Source PublicationACTA CHIMICA SINICA
ISSN0567-7351
Volume68Issue:21Pages:2222-2226
AbstractTwo porphyrin derivatives TPP-AQ and TPP-PD were synthesized and characterized The physical properties of these two molecules were studied by cyclic voltammetry, ultraviolet visible spectra, fluorescence spectra and theoretical calculations The redox potentials of TPP-AQ and TPP-PD are 1 07, 1 30 V and 1 21, 1 36 V, respectively The redox potentials of TPP-AQ are negative-shifted compared with those of TPP-PD The maximum absorptions of TPP-AQ and TPP-PD are 441 and 431 nm, respectively The maximum absorption of TPP-AQ was red-shifted compared with that of TPP-PD due to that the conjugated effect of TPP-AQ is greater than that of TPP-PD based on the results of theoretical calculations The red fluorescence peaks of TPP-AQ and TPP-PD are 657 and 656 nm, and the full widths at half-maximum of TPP-AQ and TPP-PD are 30 and 27 nm
KeywordPorphyrin Cyclic Voltammogram Fluorescence Density Functional Theory
Indexed BySCI
Language英语
WOS IDWOS:000284680400014
PublisherSCIENCE PRESS
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/70324
Collection中国科学院化学研究所
Corresponding AuthorWan Zhongquan
Affiliation1.Univ Elect Sci & Technol China, State Key Lab Elect Thin Films & Integrated Devic, Sch Microelect & Solid State Elect, Chengdu 610054, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Wan Zhongquan,Jia Chunyang,Zhang Jiaqiang,et al. Synthesis and Physical Properties of Red Emitting Materials Based on Porphyrin Derivatives[J]. ACTA CHIMICA SINICA,2010,68(21):2222-2226.
APA Wan Zhongquan,Jia Chunyang,Zhang Jiaqiang,&Zhang Guanxin.(2010).Synthesis and Physical Properties of Red Emitting Materials Based on Porphyrin Derivatives.ACTA CHIMICA SINICA,68(21),2222-2226.
MLA Wan Zhongquan,et al."Synthesis and Physical Properties of Red Emitting Materials Based on Porphyrin Derivatives".ACTA CHIMICA SINICA 68.21(2010):2222-2226.
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