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Synthesis, Structures, and Conformational Characteristics of Triptycene-Derived Calix[5]arenes
Tian, Xiao-Hong1,2; Chen, Chuan-Feng1
2010-02-05
Source PublicationORGANIC LETTERS
ISSN1523-7060
Volume12Issue:3Pages:524-527
AbstractA series of novel calix[5]arenes 5 containing one 1,8-dimethoxytriptycene moiety were synthesized through an efficient fragment coupling strategy. The subsequent demethylation of 5 with BBr(3) in dry dichloromethane gave the calix[5]arenes 6. Debutylation of both 5a similar to b and 6a similar to b with AlCl(3) resulted in the same products 7a similar to 7b. The structural studies revealed that all of the macrocyclic compounds have well-defined structures with fixed cone conformations in both solution and solid state. Moreover, it was also found that the triptycene-derived calix[5]arenes could encapsulate small neutral molecules in the solid state.
DOI10.1021/ol902758g
Indexed BySCI ; IC
Language英语
WOS IDWOS:000273982600032
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:32[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/70092
Collection中国科学院化学研究所
Corresponding AuthorChen, Chuan-Feng
Affiliation1.Chinese Acad Sci, Inst Chem, Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Tian, Xiao-Hong,Chen, Chuan-Feng. Synthesis, Structures, and Conformational Characteristics of Triptycene-Derived Calix[5]arenes[J]. ORGANIC LETTERS,2010,12(3):524-527.
APA Tian, Xiao-Hong,&Chen, Chuan-Feng.(2010).Synthesis, Structures, and Conformational Characteristics of Triptycene-Derived Calix[5]arenes.ORGANIC LETTERS,12(3),524-527.
MLA Tian, Xiao-Hong,et al."Synthesis, Structures, and Conformational Characteristics of Triptycene-Derived Calix[5]arenes".ORGANIC LETTERS 12.3(2010):524-527.
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