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Structural determinations and magnetic studies of two new binuclear complexes: azido-bridged Ni(II) dimer and di-(mu-hydroxo)-bridged Cr(III) dimer
Liang, Shengli1; Liu, Zhiliang1; Liu, Naren1; Liu, Caiming2; Di, Xiaowei1; Zhang, Jun1
2010
Source PublicationJOURNAL OF COORDINATION CHEMISTRY
ISSN0095-8972
Volume63Issue:19Pages:3441-3452
AbstractPolydentate ligands 2-[(2-hydroxypropylimino)methyl] phenol (L) and pyridine-2,6-dicarboxylic acid (H2pda) have been used in the synthesis of binuclear transition metal complexes. A new doubly end-on azido-bridged binuclear nickel(II) complex with formula [[image omitted](mu 1,1-N3)2(L)2(N3)2] center dot H2O (1) and a bis-mu-hydroxo-bridged dinuclear chromium(III) complex with the formula [[image omitted](OH)2(pda)2(H2O)2] (2) have been synthesized and characterized by single crystal X-ray diffraction and magnetic studies. Compound 1 displays intramolecular intermetallic ferromagnetic coupling with J = 28.32 cm-1 and D = -19.30 cm-1 based on the Hamiltonian H = -2JS1S2 - D([image omitted]+ [image omitted]) - gH(S1 + S2). Compound 2 displays intramolecular intermetallic antiferromagnetic coupling with J = -6.56 cm-1 based on the Hamiltonian H = -2JS1S2 - j(S1S2)2.
KeywordBinuclear Complex Crystal Structure Magnetic Properties
DOI10.1080/00958972.2010.512386
Indexed BySCI
Language英语
WOS IDWOS:000282028200012
PublisherTAYLOR & FRANCIS LTD
Citation statistics
Cited Times:14[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/70064
Collection中国科学院化学研究所
Corresponding AuthorLiu, Zhiliang
Affiliation1.Inner Mongolia Univ, Coll Chem & Chem Engn, Hohhot 010021, Peoples R China
2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Lab Organ Solids, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Liang, Shengli,Liu, Zhiliang,Liu, Naren,et al. Structural determinations and magnetic studies of two new binuclear complexes: azido-bridged Ni(II) dimer and di-(mu-hydroxo)-bridged Cr(III) dimer[J]. JOURNAL OF COORDINATION CHEMISTRY,2010,63(19):3441-3452.
APA Liang, Shengli,Liu, Zhiliang,Liu, Naren,Liu, Caiming,Di, Xiaowei,&Zhang, Jun.(2010).Structural determinations and magnetic studies of two new binuclear complexes: azido-bridged Ni(II) dimer and di-(mu-hydroxo)-bridged Cr(III) dimer.JOURNAL OF COORDINATION CHEMISTRY,63(19),3441-3452.
MLA Liang, Shengli,et al."Structural determinations and magnetic studies of two new binuclear complexes: azido-bridged Ni(II) dimer and di-(mu-hydroxo)-bridged Cr(III) dimer".JOURNAL OF COORDINATION CHEMISTRY 63.19(2010):3441-3452.
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