ICCAS OpenIR
Facile Fabrication of Honeycomb-Patterned Thin Films of Amorphous Calcium Carbonate and Mosaic Calcite
Li, Cheng; Hong, Guosong; Yu, Han; Qi, Limin
2010-05-25
Source PublicationCHEMISTRY OF MATERIALS
ISSN0897-4756
Volume22Issue:10Pages:3206-3211
AbstractFacile fabrication of honeycomb-patterned thin films of amorphous calcium carbonate (ACC) and mosaic calcite was achieved via colloidal lithography at the solution surface. At first, honeycomb-patterned ACC (HP-ACC) thin films were fabricated by a polymer-induced ACC coating of the monolayer colloidal crystal (MCC) template at the air/water interface. Subsequent controlled crystallization of the preformed HP-ACC thin films under different conditions led to honeycomb-patterned, crystalline films with different microstructures. In particular, honeycomb-patterned, mosaic calcite thin films composed of single-crystalline calcite plates could form when thermal treatment at 400 degrees C was applied to the amorphous films. Additionally, dye molecules were incoporated into the HP-ACC thin film during its formation, enabling further functionality of the patterned thin film with fluorescence. Furthermore, the highly ordered HP-ACC thin films possessed brilliant structural colors and exhibited typical photonic properties.
DOI10.1021/cm100363a
Indexed BySCI
Language英语
WOS IDWOS:000277635000025
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:38[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/70004
Collection中国科学院化学研究所
Corresponding AuthorQi, Limin
AffiliationPeking Univ, BNLMS, State Key Lab Struct Chem Unstable & Stable Speci, Coll Chem, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Li, Cheng,Hong, Guosong,Yu, Han,et al. Facile Fabrication of Honeycomb-Patterned Thin Films of Amorphous Calcium Carbonate and Mosaic Calcite[J]. CHEMISTRY OF MATERIALS,2010,22(10):3206-3211.
APA Li, Cheng,Hong, Guosong,Yu, Han,&Qi, Limin.(2010).Facile Fabrication of Honeycomb-Patterned Thin Films of Amorphous Calcium Carbonate and Mosaic Calcite.CHEMISTRY OF MATERIALS,22(10),3206-3211.
MLA Li, Cheng,et al."Facile Fabrication of Honeycomb-Patterned Thin Films of Amorphous Calcium Carbonate and Mosaic Calcite".CHEMISTRY OF MATERIALS 22.10(2010):3206-3211.
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