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Rigid and Flexible Lanthanide Complexes with an Infinite Ln-O-Ln Framework: Synthesis, Structure and Properties
Wang, Zhuo1; Bai, Feng-Ying1; Xing, Yong-Heng1; Xie, Yan1; Zeng, Xiao-Qing2; Ge, Mao-Fa2; Niu, Shu-Yun1
2010-06-01
Source PublicationJOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
ISSN1574-1443
Volume20Issue:2Pages:242-249
AbstractA series of new lanthanide coordination polymers, Ln(pydc)(Hglu) (Ln = Nd(1), Pr(2); H(2)glu = glutaric acid; 2,5-H(2)pydc = 2,5-pyridine dicarboxylic acid), have been synthesized hydrothermally from the self-assembly of the lanthanide ions (Ln(3+))with rigid 2,5-pyridine dicarboxylic acid and flexible glutaric acid. They were characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. Structural analyses reveal that both of the complexes were crystallized in monoclinic space group P2(1)/c and have intricate 3D net-structures, which contain an infinite 1D Ln-O-Ln chain structure. In addition, the phase purities of the bulk samples were identified by X-ray powder diffraction. The thermogravimetric analysis of 1 is discussed in detail.
KeywordLanthanide Complexes Glutaric Acid Crystal Structures Thermal Stability 2 5-pyridine Dicarboxylic Acid
DOI10.1007/s10904-010-9333-1
Indexed BySCI
Language英语
WOS IDWOS:000277284600006
PublisherSPRINGER
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/69978
Collection中国科学院化学研究所
Corresponding AuthorXing, Yong-Heng
Affiliation1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Wang, Zhuo,Bai, Feng-Ying,Xing, Yong-Heng,et al. Rigid and Flexible Lanthanide Complexes with an Infinite Ln-O-Ln Framework: Synthesis, Structure and Properties[J]. JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS,2010,20(2):242-249.
APA Wang, Zhuo.,Bai, Feng-Ying.,Xing, Yong-Heng.,Xie, Yan.,Zeng, Xiao-Qing.,...&Niu, Shu-Yun.(2010).Rigid and Flexible Lanthanide Complexes with an Infinite Ln-O-Ln Framework: Synthesis, Structure and Properties.JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS,20(2),242-249.
MLA Wang, Zhuo,et al."Rigid and Flexible Lanthanide Complexes with an Infinite Ln-O-Ln Framework: Synthesis, Structure and Properties".JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS 20.2(2010):242-249.
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