ICCAS OpenIR
Cleavage and Reorganization of Zr-C/Si-C Bonds Leading to Zr/Si-N Organometallic and Heterocyclic Compounds
Zhang, Shaoguang1,2; Zhang, Wen-Xiong1,2; Zhao, Jing1,2,3; Xi, Zhenfeng1,2,4
2010-10-13
Source PublicationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN0002-7863
Volume132Issue:40Pages:14042-14045
AbstractThe t-BuCN-stabilized zirconacyclopropene-azasilacyclopentadiene complexes 2 are generated in situ in high yields from the Si-tethered diynes, Cp(2)Zr(II) species, and 2 equiv of t-BuCN via a coordination-induced Zr-C/Si-C bond cleavage and reorganization. Complexes 2 have been demonstrated to be synthetically very useful. A variety of novel Zr/Si organo-bimetallic compounds and Si/N heterocyclic compounds, such as azasilacyclopentadienes, azasilacyclohexadienes, and allenylazazirconacycles, are obtained in high yields when complexes 2 are treated with ketones, carbodiimides, alkynes, elemental sulfur (S(8)), acid chlorides, or nitriles. In this chemistry, t-BuCN behaves as both an initiator and a brake/release handle to initiate and control the reaction process.
DOI10.1021/ja1074932
Indexed BySCI ; IC
Language英语
WOS IDWOS:000282660100032
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:43[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/69910
Collection中国科学院化学研究所
Corresponding AuthorXi, Zhenfeng
Affiliation1.Peking Univ, BNLMS, Coll Chem, Minist Educ, Beijing 100871, Peoples R China
2.Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Coll Chem, Minist Educ, Beijing 100871, Peoples R China
3.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
4.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Shaoguang,Zhang, Wen-Xiong,Zhao, Jing,et al. Cleavage and Reorganization of Zr-C/Si-C Bonds Leading to Zr/Si-N Organometallic and Heterocyclic Compounds[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2010,132(40):14042-14045.
APA Zhang, Shaoguang,Zhang, Wen-Xiong,Zhao, Jing,&Xi, Zhenfeng.(2010).Cleavage and Reorganization of Zr-C/Si-C Bonds Leading to Zr/Si-N Organometallic and Heterocyclic Compounds.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,132(40),14042-14045.
MLA Zhang, Shaoguang,et al."Cleavage and Reorganization of Zr-C/Si-C Bonds Leading to Zr/Si-N Organometallic and Heterocyclic Compounds".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 132.40(2010):14042-14045.
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