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Study of the Photodissociation Process of ClC(O)SCH3 Using both Synchrotron Radiation and HeI Photoelectron Spectroscopy in the Valence Region
Gerones, Mariana1; Erben, Mauricio F.1; Ge, Maofa3; Cavasso Filho, Reinaldo L.4; Romano, Rosana M.1; Della Vedova, Carlos O.1,2
2010-08-12
Source PublicationJOURNAL OF PHYSICAL CHEMISTRY A
ISSN1089-5639
Volume114Issue:31Pages:8049-8055
AbstractThe simultaneous evaluation of the PES and valence synchrotron photoionization studies complemented by the results of quantum chemical calculations offers unusually detailed insights into the valence ionization processes of small covalent molecules. Thus, methyl thiochloroformate, ClC(O)SCH3, has been investigated by using results from both photoelectron spectroscopy (PES) and synchrotron radiation in the valence energy range. In an additional series of experiments, total ion yield (TIY) and photoelectron-photoion coincidence (PEPICO) spectra have been recorded. Furthermore, the relative yields for ionic fragments have been determined as a function of the photon energy. Vibronic structure has been observed in the TIY spectrum recorded in the synchrotron experiments. The photodissociation behavior of ClC(O)SCH3 can be divided into two well-defined energy regions.
DOI10.1021/jp102179w
Indexed BySCI
Language英语
WOS IDWOS:000280523500004
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:9[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/69834
Collection中国科学院化学研究所
Corresponding AuthorErben, Mauricio F.
Affiliation1.Univ Nacl La Plata, Fac Ciencias Exactas, Dept Quim, CEQUINOR CONICET UNLP, RA-1900 La Plata, Buenos Aires, Argentina
2.UNLP CIC CONICET, LaSeISiC, RA-1903 Gonnet, Argentina
3.Chinese Acad Sci, State Key Lab Struct Chem Unstable & Stable Speci, BNLMS, Inst Chem, Beijing 100080, Peoples R China
4.Univ Fed ABC, BR-09090400 Sao Paulo, Brazil
Recommended Citation
GB/T 7714
Gerones, Mariana,Erben, Mauricio F.,Ge, Maofa,et al. Study of the Photodissociation Process of ClC(O)SCH3 Using both Synchrotron Radiation and HeI Photoelectron Spectroscopy in the Valence Region[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2010,114(31):8049-8055.
APA Gerones, Mariana,Erben, Mauricio F.,Ge, Maofa,Cavasso Filho, Reinaldo L.,Romano, Rosana M.,&Della Vedova, Carlos O..(2010).Study of the Photodissociation Process of ClC(O)SCH3 Using both Synchrotron Radiation and HeI Photoelectron Spectroscopy in the Valence Region.JOURNAL OF PHYSICAL CHEMISTRY A,114(31),8049-8055.
MLA Gerones, Mariana,et al."Study of the Photodissociation Process of ClC(O)SCH3 Using both Synchrotron Radiation and HeI Photoelectron Spectroscopy in the Valence Region".JOURNAL OF PHYSICAL CHEMISTRY A 114.31(2010):8049-8055.
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